Improved calibration procedures and new standards for U–Pb and Th–Pb dating of Phanerozoic xenotime by ion microprobe

Xenotime is a widely occurring mineral that is amenable to U–Pb and Th–Pb dating but often is found as micrometre-sized crystals that can only be dated by in situ microanalytical techniques. Determining accurate ages for Phanerozoic samples, and assessing concordance in older samples, requires accur...

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Main Authors: Fletcher, Ian, McNaughton, Neal, Aleinikoff, J., Rasmussen, Birger, Kamo, S.
Format: Journal Article
Published: Elsevier Science BV 2004
Subjects:
Online Access:http://hdl.handle.net/20.500.11937/35559
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author Fletcher, Ian
McNaughton, Neal
Aleinikoff, J.
Rasmussen, Birger
Kamo, S.
author_facet Fletcher, Ian
McNaughton, Neal
Aleinikoff, J.
Rasmussen, Birger
Kamo, S.
author_sort Fletcher, Ian
building Curtin Institutional Repository
collection Online Access
description Xenotime is a widely occurring mineral that is amenable to U–Pb and Th–Pb dating but often is found as micrometre-sized crystals that can only be dated by in situ microanalytical techniques. Determining accurate ages for Phanerozoic samples, and assessing concordance in older samples, requires accurate determination of Pb/U and Pb/Th; however, ion microprobe data for these ratios are affected by the highly variable trace element composition of xenotime. We have identified calibration procedures, including matrix corrections for the effects of the dominant trace elements U, Th and REE, that provide an accuracy of ~1% for Pb/U and <2% for Pb/Th. Several new standard samples are available that cover a range of compositions, permitting better matching of samples with standards as well as giving control of the matrix effects. However, no chemically homogeneous samples have been identified.
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publishDate 2004
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spelling curtin-20.500.11937-355592017-09-13T15:52:27Z Improved calibration procedures and new standards for U–Pb and Th–Pb dating of Phanerozoic xenotime by ion microprobe Fletcher, Ian McNaughton, Neal Aleinikoff, J. Rasmussen, Birger Kamo, S. Th–Pb SHRIMP U–Pb Xenotime Standards Geochronology Xenotime is a widely occurring mineral that is amenable to U–Pb and Th–Pb dating but often is found as micrometre-sized crystals that can only be dated by in situ microanalytical techniques. Determining accurate ages for Phanerozoic samples, and assessing concordance in older samples, requires accurate determination of Pb/U and Pb/Th; however, ion microprobe data for these ratios are affected by the highly variable trace element composition of xenotime. We have identified calibration procedures, including matrix corrections for the effects of the dominant trace elements U, Th and REE, that provide an accuracy of ~1% for Pb/U and <2% for Pb/Th. Several new standard samples are available that cover a range of compositions, permitting better matching of samples with standards as well as giving control of the matrix effects. However, no chemically homogeneous samples have been identified. 2004 Journal Article http://hdl.handle.net/20.500.11937/35559 10.1016/j.chemgeo.2004.06.015 Elsevier Science BV restricted
spellingShingle Th–Pb
SHRIMP
U–Pb
Xenotime
Standards
Geochronology
Fletcher, Ian
McNaughton, Neal
Aleinikoff, J.
Rasmussen, Birger
Kamo, S.
Improved calibration procedures and new standards for U–Pb and Th–Pb dating of Phanerozoic xenotime by ion microprobe
title Improved calibration procedures and new standards for U–Pb and Th–Pb dating of Phanerozoic xenotime by ion microprobe
title_full Improved calibration procedures and new standards for U–Pb and Th–Pb dating of Phanerozoic xenotime by ion microprobe
title_fullStr Improved calibration procedures and new standards for U–Pb and Th–Pb dating of Phanerozoic xenotime by ion microprobe
title_full_unstemmed Improved calibration procedures and new standards for U–Pb and Th–Pb dating of Phanerozoic xenotime by ion microprobe
title_short Improved calibration procedures and new standards for U–Pb and Th–Pb dating of Phanerozoic xenotime by ion microprobe
title_sort improved calibration procedures and new standards for u–pb and th–pb dating of phanerozoic xenotime by ion microprobe
topic Th–Pb
SHRIMP
U–Pb
Xenotime
Standards
Geochronology
url http://hdl.handle.net/20.500.11937/35559