Chemicals in reverse osmosis-treated wastewater: occurrence, health risk and contribution to residual dissolved organic carbon

The quality and safety of reverse osmosis (RO)-treated secondary wastewater, for indirect The quality and safety of reverse osmosis (RO)-treated secondary wastewater, for indirect potable re-use, was assessed using a dataset of 375 chemicals measured in RO-treated wastewater. A screening health risk...

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Main Authors: Linge, Kathryn, Blair, Palenque, Busetti, Francesco, Rodriguez, C, Heitz, Anna
Format: Journal Article
Published: IWA Publishing 2012
Subjects:
Online Access:http://hdl.handle.net/20.500.11937/34814
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author Linge, Kathryn
Blair, Palenque
Busetti, Francesco
Rodriguez, C
Heitz, Anna
author_facet Linge, Kathryn
Blair, Palenque
Busetti, Francesco
Rodriguez, C
Heitz, Anna
author_sort Linge, Kathryn
building Curtin Institutional Repository
collection Online Access
description The quality and safety of reverse osmosis (RO)-treated secondary wastewater, for indirect The quality and safety of reverse osmosis (RO)-treated secondary wastewater, for indirect potable re-use, was assessed using a dataset of 375 chemicals measured in RO-treated wastewater. A screening health risk assessment indicated that four N-nitrosamines were of potential concern, although median concentrations of these chemicals were always below health values. The most frequently detected chemicals in RO-treated water were disinfection by-products, volatile organic compounds, metals and complexing agents, in contrast to many monitoring programs that focus on pharmaceuticals, personal care products and hormones. Frequent detections in RO-treated wastewater were most related to high concentrations in secondary wastewater, relative to limit of reporting, and the potential for chemicals to form or be added during the treatment process, rather than poor rejection by RO membranes. Between 3.7 and 10.7 µg/L of dissolved organic carbon (DOC) in RO permeate could be attributed from chemicals detected on at least one occasion, with the majority of this total attributed to chemicals detected in less than 25% of samples. While chemicals below detection may contribute a significant component of DOC, it is likely that natural organic matter and soluble microbial products still contribute the majority of DOC to RO permeate. A high degree of safety is demonstrated for the use of RO-treated wastewater as an indirect source of potable water.
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spelling curtin-20.500.11937-348142019-02-19T04:27:41Z Chemicals in reverse osmosis-treated wastewater: occurrence, health risk and contribution to residual dissolved organic carbon Linge, Kathryn Blair, Palenque Busetti, Francesco Rodriguez, C Heitz, Anna groundwater replenishment indirect potable reuse water recycling screening health risk assessment reverse osmosis chemical risk The quality and safety of reverse osmosis (RO)-treated secondary wastewater, for indirect The quality and safety of reverse osmosis (RO)-treated secondary wastewater, for indirect potable re-use, was assessed using a dataset of 375 chemicals measured in RO-treated wastewater. A screening health risk assessment indicated that four N-nitrosamines were of potential concern, although median concentrations of these chemicals were always below health values. The most frequently detected chemicals in RO-treated water were disinfection by-products, volatile organic compounds, metals and complexing agents, in contrast to many monitoring programs that focus on pharmaceuticals, personal care products and hormones. Frequent detections in RO-treated wastewater were most related to high concentrations in secondary wastewater, relative to limit of reporting, and the potential for chemicals to form or be added during the treatment process, rather than poor rejection by RO membranes. Between 3.7 and 10.7 µg/L of dissolved organic carbon (DOC) in RO permeate could be attributed from chemicals detected on at least one occasion, with the majority of this total attributed to chemicals detected in less than 25% of samples. While chemicals below detection may contribute a significant component of DOC, it is likely that natural organic matter and soluble microbial products still contribute the majority of DOC to RO permeate. A high degree of safety is demonstrated for the use of RO-treated wastewater as an indirect source of potable water. 2012 Journal Article http://hdl.handle.net/20.500.11937/34814 10.2166/aqua.2012.047 IWA Publishing fulltext
spellingShingle groundwater replenishment
indirect potable reuse
water recycling
screening health risk assessment
reverse osmosis
chemical risk
Linge, Kathryn
Blair, Palenque
Busetti, Francesco
Rodriguez, C
Heitz, Anna
Chemicals in reverse osmosis-treated wastewater: occurrence, health risk and contribution to residual dissolved organic carbon
title Chemicals in reverse osmosis-treated wastewater: occurrence, health risk and contribution to residual dissolved organic carbon
title_full Chemicals in reverse osmosis-treated wastewater: occurrence, health risk and contribution to residual dissolved organic carbon
title_fullStr Chemicals in reverse osmosis-treated wastewater: occurrence, health risk and contribution to residual dissolved organic carbon
title_full_unstemmed Chemicals in reverse osmosis-treated wastewater: occurrence, health risk and contribution to residual dissolved organic carbon
title_short Chemicals in reverse osmosis-treated wastewater: occurrence, health risk and contribution to residual dissolved organic carbon
title_sort chemicals in reverse osmosis-treated wastewater: occurrence, health risk and contribution to residual dissolved organic carbon
topic groundwater replenishment
indirect potable reuse
water recycling
screening health risk assessment
reverse osmosis
chemical risk
url http://hdl.handle.net/20.500.11937/34814