Mass transfer and trace element redistribution during hydration of granulites in the Bergen Arcs, Norway

The Bergen Arcs, located on the western coast of Norway, are characterized by Precambrian granulite facies rocks partially hydrated at amphibolite and eclogite facies conditions. At Hilland Radöy, granulite displays sharp hydration fronts across which the granulite facies assemblage composed of garn...

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Main Authors: Centrella, S., Austrheim, H., Putnis, Andrew
Format: Journal Article
Published: Elsevier BV 2016
Online Access:http://hdl.handle.net/20.500.11937/34267
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author Centrella, S.
Austrheim, H.
Putnis, Andrew
author_facet Centrella, S.
Austrheim, H.
Putnis, Andrew
author_sort Centrella, S.
building Curtin Institutional Repository
collection Online Access
description The Bergen Arcs, located on the western coast of Norway, are characterized by Precambrian granulite facies rocks partially hydrated at amphibolite and eclogite facies conditions. At Hilland Radöy, granulite displays sharp hydration fronts across which the granulite facies assemblage composed of garnet (55%) and clinopyroxene (45%) is replaced by an amphibolite facies mineralogy defined by chlorite, epidote, and amphibole. The replacement of both phases is pseudomorphic and the overall reaction is isovolumetric. In the present study, LA ICPMS has been used to determine the trace element redistribution during the hydration. Although the bulk concentrations of the trace elements do not change, the LILE, HFSE, and REE losses and gains in replacing the garnet are qualitatively balanced by the opposite gains and losses associated with the replacement of clinopyroxene. From the REE compositions of the parent granulite and the product amphibolite, measured in µg/cm3, we conclude that the mass of rock lost to the fluid phase during the hydration is approximately 20%. This suggests a mechanism for coupling between the local stress generated by hydration reactions and mass transfer, dependent on the spatial scale over which the system is open.
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spelling curtin-20.500.11937-342672017-09-13T15:13:27Z Mass transfer and trace element redistribution during hydration of granulites in the Bergen Arcs, Norway Centrella, S. Austrheim, H. Putnis, Andrew The Bergen Arcs, located on the western coast of Norway, are characterized by Precambrian granulite facies rocks partially hydrated at amphibolite and eclogite facies conditions. At Hilland Radöy, granulite displays sharp hydration fronts across which the granulite facies assemblage composed of garnet (55%) and clinopyroxene (45%) is replaced by an amphibolite facies mineralogy defined by chlorite, epidote, and amphibole. The replacement of both phases is pseudomorphic and the overall reaction is isovolumetric. In the present study, LA ICPMS has been used to determine the trace element redistribution during the hydration. Although the bulk concentrations of the trace elements do not change, the LILE, HFSE, and REE losses and gains in replacing the garnet are qualitatively balanced by the opposite gains and losses associated with the replacement of clinopyroxene. From the REE compositions of the parent granulite and the product amphibolite, measured in µg/cm3, we conclude that the mass of rock lost to the fluid phase during the hydration is approximately 20%. This suggests a mechanism for coupling between the local stress generated by hydration reactions and mass transfer, dependent on the spatial scale over which the system is open. 2016 Journal Article http://hdl.handle.net/20.500.11937/34267 10.1016/j.lithos.2016.06.019 Elsevier BV restricted
spellingShingle Centrella, S.
Austrheim, H.
Putnis, Andrew
Mass transfer and trace element redistribution during hydration of granulites in the Bergen Arcs, Norway
title Mass transfer and trace element redistribution during hydration of granulites in the Bergen Arcs, Norway
title_full Mass transfer and trace element redistribution during hydration of granulites in the Bergen Arcs, Norway
title_fullStr Mass transfer and trace element redistribution during hydration of granulites in the Bergen Arcs, Norway
title_full_unstemmed Mass transfer and trace element redistribution during hydration of granulites in the Bergen Arcs, Norway
title_short Mass transfer and trace element redistribution during hydration of granulites in the Bergen Arcs, Norway
title_sort mass transfer and trace element redistribution during hydration of granulites in the bergen arcs, norway
url http://hdl.handle.net/20.500.11937/34267