TEMPO Monolayers on Si(100) Electrodes: Electrostatic Effects by the Electrolyte and Semiconductor Space-Charge on the Electroactivity of a Persistent Radical.

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TEMPO Monolayers on Si(100) Electrodes: Electrostatic Effects by the Electrolyte and Semiconductor Space-Charge on the Electroactivity of a Persistent Radical.

This work demonstrates the effect of electrostatic interactions on the electroactivity of a persistent organic free radical. This was achieved by chemisorption of molecules of 4-azido-2,2,6,6-tetramethyl-1-piperdinyloxy (4-azido-TEMPO) onto monolayer-modified Si(100) electrodes using a two-step chem...

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Bibliographic Details
Main Authors:	Zhang, L., Vogel, Y., Noble, B., Gonçales, V., Darwish, N., Brun, A., Gooding, J., Wallace, G., Coote, M., Ciampi, Simone
Format:	Journal Article
Published:	American Chemical Society 2016
Online Access:	http://hdl.handle.net/20.500.11937/33930

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