Advances in Cathode Materials for Solid Oxide Fuel Cells: Complex Oxides without Alkaline Earth Metal Elements

Solid oxide fuel cells (SOFCs) represent one of the cleanest and most efficient options for the direct conversion of a wide variety of fuels to electricity. For example, SOFCs powered by natural gas are ideally suited for distributed power generation. However, the commercialization of SOFC technolog...

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Main Authors: Chen, Y., Zhou, W., Ding, D., Liu, M., Ciucci, F., Tade, Moses, Shao, Zongping
Format: Journal Article
Published: Wiley-VCH Verlag 2015
Online Access:http://hdl.handle.net/20.500.11937/33593
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author Chen, Y.
Zhou, W.
Ding, D.
Liu, M.
Ciucci, F.
Tade, Moses
Shao, Zongping
author_facet Chen, Y.
Zhou, W.
Ding, D.
Liu, M.
Ciucci, F.
Tade, Moses
Shao, Zongping
author_sort Chen, Y.
building Curtin Institutional Repository
collection Online Access
description Solid oxide fuel cells (SOFCs) represent one of the cleanest and most efficient options for the direct conversion of a wide variety of fuels to electricity. For example, SOFCs powered by natural gas are ideally suited for distributed power generation. However, the commercialization of SOFC technologies hinges on breakthroughs in materials development to dramatically reduce the cost while enhancing performance and durability. One of the critical obstacles to achieving high-performance SOFC systems is the cathodes for oxygen reduction reaction (ORR), which perform poorly at low temperatures and degrade over time under operating conditions. Here a comprehensive review of the latest advances in the development of SOFC cathodes is presented: complex oxides without alkaline earth metal elements (because these elements could be vulnerable to phase segregation and contaminant poisoning). Various strategies are discussed for enhancing ORR activity while minimizing the effect of contaminant on electrode durability. Furthermore, some of the critical challenges are briefly highlighted and the prospects for future-generation SOFC cathodes are discussed. A good understanding of the latest advances and remaining challenges in searching for highly active SOFC cathodes with robust tolerance to contaminants may provide useful guidance for the rational design of new materials and structures for commercially viable SOFC technologies.
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publishDate 2015
publisher Wiley-VCH Verlag
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spelling curtin-20.500.11937-335932017-09-13T15:31:15Z Advances in Cathode Materials for Solid Oxide Fuel Cells: Complex Oxides without Alkaline Earth Metal Elements Chen, Y. Zhou, W. Ding, D. Liu, M. Ciucci, F. Tade, Moses Shao, Zongping Solid oxide fuel cells (SOFCs) represent one of the cleanest and most efficient options for the direct conversion of a wide variety of fuels to electricity. For example, SOFCs powered by natural gas are ideally suited for distributed power generation. However, the commercialization of SOFC technologies hinges on breakthroughs in materials development to dramatically reduce the cost while enhancing performance and durability. One of the critical obstacles to achieving high-performance SOFC systems is the cathodes for oxygen reduction reaction (ORR), which perform poorly at low temperatures and degrade over time under operating conditions. Here a comprehensive review of the latest advances in the development of SOFC cathodes is presented: complex oxides without alkaline earth metal elements (because these elements could be vulnerable to phase segregation and contaminant poisoning). Various strategies are discussed for enhancing ORR activity while minimizing the effect of contaminant on electrode durability. Furthermore, some of the critical challenges are briefly highlighted and the prospects for future-generation SOFC cathodes are discussed. A good understanding of the latest advances and remaining challenges in searching for highly active SOFC cathodes with robust tolerance to contaminants may provide useful guidance for the rational design of new materials and structures for commercially viable SOFC technologies. 2015 Journal Article http://hdl.handle.net/20.500.11937/33593 10.1002/aenm.201500537 Wiley-VCH Verlag restricted
spellingShingle Chen, Y.
Zhou, W.
Ding, D.
Liu, M.
Ciucci, F.
Tade, Moses
Shao, Zongping
Advances in Cathode Materials for Solid Oxide Fuel Cells: Complex Oxides without Alkaline Earth Metal Elements
title Advances in Cathode Materials for Solid Oxide Fuel Cells: Complex Oxides without Alkaline Earth Metal Elements
title_full Advances in Cathode Materials for Solid Oxide Fuel Cells: Complex Oxides without Alkaline Earth Metal Elements
title_fullStr Advances in Cathode Materials for Solid Oxide Fuel Cells: Complex Oxides without Alkaline Earth Metal Elements
title_full_unstemmed Advances in Cathode Materials for Solid Oxide Fuel Cells: Complex Oxides without Alkaline Earth Metal Elements
title_short Advances in Cathode Materials for Solid Oxide Fuel Cells: Complex Oxides without Alkaline Earth Metal Elements
title_sort advances in cathode materials for solid oxide fuel cells: complex oxides without alkaline earth metal elements
url http://hdl.handle.net/20.500.11937/33593