Calixarene complexes of anion-bridged oligouranyl species
The syntheses and structures of uranyl complexes of p-t-Bu-calix[6]arene (calix[6]H6) and p-t-Bu-calix[9]arene(calix[9]H9) are reported, further developing the role of calixarenes as 'cluster keepers'. The calix[6]arene com-plex, formulated as [(HO){UO2(calix[6]H4)(dmso)}3H], is trinuclear...
| Main Authors: | , , , , , , |
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| Format: | Journal Article |
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Taylor & Francis
2004
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| Online Access: | http://hdl.handle.net/20.500.11937/3358 |
| _version_ | 1848744209624858624 |
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| author | DeLaigue, X. Gutsche, C. Harrowfield, J. Ogden, Mark Skelton, B. Stewart, D. White, A. |
| author_facet | DeLaigue, X. Gutsche, C. Harrowfield, J. Ogden, Mark Skelton, B. Stewart, D. White, A. |
| author_sort | DeLaigue, X. |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | The syntheses and structures of uranyl complexes of p-t-Bu-calix[6]arene (calix[6]H6) and p-t-Bu-calix[9]arene(calix[9]H9) are reported, further developing the role of calixarenes as 'cluster keepers'. The calix[6]arene com-plex, formulated as [(HO){UO2(calix[6]H4)(dmso)}3H], is trinuclear and linked symmetrically by the hydroxyl O atom. The calix[9]arene complex is binuclear, with a carbonate atom bridging between the two uranyl cations to give the complex, (HNEt3)3[(OCO2)(UO2)3(calix[9]H4)]. |
| first_indexed | 2025-11-14T05:57:50Z |
| format | Journal Article |
| id | curtin-20.500.11937-3358 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T05:57:50Z |
| publishDate | 2004 |
| publisher | Taylor & Francis |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-33582019-02-19T05:34:53Z Calixarene complexes of anion-bridged oligouranyl species DeLaigue, X. Gutsche, C. Harrowfield, J. Ogden, Mark Skelton, B. Stewart, D. White, A. cluster keeper calixarene uranyl The syntheses and structures of uranyl complexes of p-t-Bu-calix[6]arene (calix[6]H6) and p-t-Bu-calix[9]arene(calix[9]H9) are reported, further developing the role of calixarenes as 'cluster keepers'. The calix[6]arene com-plex, formulated as [(HO){UO2(calix[6]H4)(dmso)}3H], is trinuclear and linked symmetrically by the hydroxyl O atom. The calix[9]arene complex is binuclear, with a carbonate atom bridging between the two uranyl cations to give the complex, (HNEt3)3[(OCO2)(UO2)3(calix[9]H4)]. 2004 Journal Article http://hdl.handle.net/20.500.11937/3358 10.1080/10610270412331318827 Taylor & Francis fulltext |
| spellingShingle | cluster keeper calixarene uranyl DeLaigue, X. Gutsche, C. Harrowfield, J. Ogden, Mark Skelton, B. Stewart, D. White, A. Calixarene complexes of anion-bridged oligouranyl species |
| title | Calixarene complexes of anion-bridged oligouranyl species |
| title_full | Calixarene complexes of anion-bridged oligouranyl species |
| title_fullStr | Calixarene complexes of anion-bridged oligouranyl species |
| title_full_unstemmed | Calixarene complexes of anion-bridged oligouranyl species |
| title_short | Calixarene complexes of anion-bridged oligouranyl species |
| title_sort | calixarene complexes of anion-bridged oligouranyl species |
| topic | cluster keeper calixarene uranyl |
| url | http://hdl.handle.net/20.500.11937/3358 |