Leaching characteristics of inherent inorganic nutrients in biochars from the slow and fast pyrolysis of mallee biomass

This study compares the inherent leaching characteristics of inorganic nutrients, particularly alkali and alkaline earth metallic (AAEM, mainly Na, K, Mg, and Ca) species in biochars prepared from the slow and fast pyrolysis of mallee biomass particles at 500 C. The results indicate that, compared t...

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Main Authors: Kong, Zhao Ying, Liaw, Sui Boon, Gao, Xiangpeng, Yu, Yun, Wu, Hongwei
Format: Journal Article
Published: Elsevier Ltd 2014
Online Access:http://hdl.handle.net/20.500.11937/3334
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author Kong, Zhao Ying
Liaw, Sui Boon
Gao, Xiangpeng
Yu, Yun
Wu, Hongwei
author_facet Kong, Zhao Ying
Liaw, Sui Boon
Gao, Xiangpeng
Yu, Yun
Wu, Hongwei
author_sort Kong, Zhao Ying
building Curtin Institutional Repository
collection Online Access
description This study compares the inherent leaching characteristics of inorganic nutrients, particularly alkali and alkaline earth metallic (AAEM, mainly Na, K, Mg, and Ca) species in biochars prepared from the slow and fast pyrolysis of mallee biomass particles at 500 C. The results indicate that, compared to slow pyrolysis, fast pyrolysis produces biochars with less water-soluble AAEM species but more plant available AAEM nutrient species (through Mehlich I extraction). Pyrolysis of different biomass components results in biochars with different water-soluble and plant available AAEM nutrient species, depending on pyrolysis conditions. Biochars produced from pyrolysis of large wood particle (2–4 mm) exhibit slower water leaching kinetics and a lower plant available nutrients than those from fine wood particles (150–250 lm). Slow pyrolysis results in a reduction in water-soluble Na and K in biochars while an increment was observed for biochars produced from the fast pyrolysis of large wood. Experimental kinetic data can be broadly fitted to a pseudo-second order model. For all biochars, a significant proportion of inorganic nutrients can be recycled, demonstrating the potential of returning biochar to soil for completing the loop of nutrient recycling and enhancing the sustainability of biomass utilisation cycle.
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institution Curtin University Malaysia
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last_indexed 2025-11-14T05:57:43Z
publishDate 2014
publisher Elsevier Ltd
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spelling curtin-20.500.11937-33342017-09-13T16:06:10Z Leaching characteristics of inherent inorganic nutrients in biochars from the slow and fast pyrolysis of mallee biomass Kong, Zhao Ying Liaw, Sui Boon Gao, Xiangpeng Yu, Yun Wu, Hongwei This study compares the inherent leaching characteristics of inorganic nutrients, particularly alkali and alkaline earth metallic (AAEM, mainly Na, K, Mg, and Ca) species in biochars prepared from the slow and fast pyrolysis of mallee biomass particles at 500 C. The results indicate that, compared to slow pyrolysis, fast pyrolysis produces biochars with less water-soluble AAEM species but more plant available AAEM nutrient species (through Mehlich I extraction). Pyrolysis of different biomass components results in biochars with different water-soluble and plant available AAEM nutrient species, depending on pyrolysis conditions. Biochars produced from pyrolysis of large wood particle (2–4 mm) exhibit slower water leaching kinetics and a lower plant available nutrients than those from fine wood particles (150–250 lm). Slow pyrolysis results in a reduction in water-soluble Na and K in biochars while an increment was observed for biochars produced from the fast pyrolysis of large wood. Experimental kinetic data can be broadly fitted to a pseudo-second order model. For all biochars, a significant proportion of inorganic nutrients can be recycled, demonstrating the potential of returning biochar to soil for completing the loop of nutrient recycling and enhancing the sustainability of biomass utilisation cycle. 2014 Journal Article http://hdl.handle.net/20.500.11937/3334 10.1016/j.fuel.2014.03.025 Elsevier Ltd restricted
spellingShingle Kong, Zhao Ying
Liaw, Sui Boon
Gao, Xiangpeng
Yu, Yun
Wu, Hongwei
Leaching characteristics of inherent inorganic nutrients in biochars from the slow and fast pyrolysis of mallee biomass
title Leaching characteristics of inherent inorganic nutrients in biochars from the slow and fast pyrolysis of mallee biomass
title_full Leaching characteristics of inherent inorganic nutrients in biochars from the slow and fast pyrolysis of mallee biomass
title_fullStr Leaching characteristics of inherent inorganic nutrients in biochars from the slow and fast pyrolysis of mallee biomass
title_full_unstemmed Leaching characteristics of inherent inorganic nutrients in biochars from the slow and fast pyrolysis of mallee biomass
title_short Leaching characteristics of inherent inorganic nutrients in biochars from the slow and fast pyrolysis of mallee biomass
title_sort leaching characteristics of inherent inorganic nutrients in biochars from the slow and fast pyrolysis of mallee biomass
url http://hdl.handle.net/20.500.11937/3334