Syntheses, Spectroscopic, Electrochemical, and Third-Order Nonlinear Optical Studies of a Hybrid Tris{ruthenium(alkynyl)/(2-phenylpyridine)}iridium Complex

Syntheses, Spectroscopic, Electrochemical, and Third-Order Nonlinear Optical Studies of a Hybrid Tris{ruthenium(alkynyl)/(2-phenylpyridine)}iridium Complex

The synthesis of fac-[Ir{N,C1′-(2,2′-NC5H4C6H3-5′-C C-1-C6H2-3,5-Et2-4-C CC6H4-4-C CH)}3] (10), which bears pendant ethynyl groups, and its reaction with [RuCl(dppe)2]PF6 to afford the heterobimetallic complex fac-[Ir{N,C1′-(2,2′-NC5H4C6H3-5′-C C-1-C6H2-3,5-Et2-4-C CC6H4-4-C C-trans-[RuCl(dppe)2])}3...

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Bibliographic Details
Main Authors: Zhao, H., Simpson, Peter, Barlow, A., Moxey, G., Morshedi, M., Roy, N., Philip, R., Zhang, C., Cifuentes, M., Humphrey, M.
Format: Journal Article
Published: 2015
Online Access:http://hdl.handle.net/20.500.11937/33156

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