New anhydrous proton exchange membranes for high-temperature fuel cells based on PVDF–PVP blended polymers
A novel high-temperature proton exchange membrane (PEM) consisting of polyvinylpyrrolidone (PVP) and polyvinylidene fluoride (PVDF) has been successfully prepared by a simple and scalable polymer blending method. PVP is miscible with PVDF, forming a single-phased PVDF–PVP polymer with excellent flow...
| Main Authors: | , , , , |
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| Format: | Journal Article |
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R S C Publications
2015
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| Online Access: | http://hdl.handle.net/20.500.11937/32959 |
| _version_ | 1848753811822215168 |
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| author | Guo, Z. Xu, X. Xiang, Y. Lu, S. Jiang, San Ping |
| author_facet | Guo, Z. Xu, X. Xiang, Y. Lu, S. Jiang, San Ping |
| author_sort | Guo, Z. |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | A novel high-temperature proton exchange membrane (PEM) consisting of polyvinylpyrrolidone (PVP) and polyvinylidene fluoride (PVDF) has been successfully prepared by a simple and scalable polymer blending method. PVP is miscible with PVDF, forming a single-phased PVDF–PVP polymer with excellent flowability and uniform microstructure when the PVP content is equal to or higher than 40 wt% due to the effective hydrogen bonding between the functional groups of PVP and PVDF. A proton conductivity of 0.093 S cm1 was obtained for a 20 wt% PVDF–80 wt% PVP membrane with a H3PO4 doping level of 2.7 at 200 C under anhydrous conditions, compatible with the state-of-the-art PBI/PA membranes. PEM fuel cells with PA/PVDF–PVP membranes showed a high power density of 530 mW cm2 at 180 C in H2/O2 and excellent stability without external humidification. The results indicate the high structural and chemical stability and high retention capability of the blended membranes for doped PA at elevated operation temperatures. The PVDF–PVP hybrids show promising potential as alternative PEMs for fuelcells at elevated high temperatures and under anhydrous conditions. |
| first_indexed | 2025-11-14T08:30:27Z |
| format | Journal Article |
| id | curtin-20.500.11937-32959 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T08:30:27Z |
| publishDate | 2015 |
| publisher | R S C Publications |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-329592017-09-13T15:27:37Z New anhydrous proton exchange membranes for high-temperature fuel cells based on PVDF–PVP blended polymers Guo, Z. Xu, X. Xiang, Y. Lu, S. Jiang, San Ping A novel high-temperature proton exchange membrane (PEM) consisting of polyvinylpyrrolidone (PVP) and polyvinylidene fluoride (PVDF) has been successfully prepared by a simple and scalable polymer blending method. PVP is miscible with PVDF, forming a single-phased PVDF–PVP polymer with excellent flowability and uniform microstructure when the PVP content is equal to or higher than 40 wt% due to the effective hydrogen bonding between the functional groups of PVP and PVDF. A proton conductivity of 0.093 S cm1 was obtained for a 20 wt% PVDF–80 wt% PVP membrane with a H3PO4 doping level of 2.7 at 200 C under anhydrous conditions, compatible with the state-of-the-art PBI/PA membranes. PEM fuel cells with PA/PVDF–PVP membranes showed a high power density of 530 mW cm2 at 180 C in H2/O2 and excellent stability without external humidification. The results indicate the high structural and chemical stability and high retention capability of the blended membranes for doped PA at elevated operation temperatures. The PVDF–PVP hybrids show promising potential as alternative PEMs for fuelcells at elevated high temperatures and under anhydrous conditions. 2015 Journal Article http://hdl.handle.net/20.500.11937/32959 10.1039/c4ta04952g R S C Publications restricted |
| spellingShingle | Guo, Z. Xu, X. Xiang, Y. Lu, S. Jiang, San Ping New anhydrous proton exchange membranes for high-temperature fuel cells based on PVDF–PVP blended polymers |
| title | New anhydrous proton exchange membranes for high-temperature fuel cells based on PVDF–PVP blended polymers |
| title_full | New anhydrous proton exchange membranes for high-temperature fuel cells based on PVDF–PVP blended polymers |
| title_fullStr | New anhydrous proton exchange membranes for high-temperature fuel cells based on PVDF–PVP blended polymers |
| title_full_unstemmed | New anhydrous proton exchange membranes for high-temperature fuel cells based on PVDF–PVP blended polymers |
| title_short | New anhydrous proton exchange membranes for high-temperature fuel cells based on PVDF–PVP blended polymers |
| title_sort | new anhydrous proton exchange membranes for high-temperature fuel cells based on pvdf–pvp blended polymers |
| url | http://hdl.handle.net/20.500.11937/32959 |