Impact of NOM character on copper adsorption by trace ferric hydroxide from iron corrosion in water supply system
The fate of trace concentrations of cupric sulfate (<0.4 mg/L) dosed into chloraminated distribution systems to inhibit nitrification has been shown in this study to be controlled by at least two crucial factors: the character of natural organic matter (NOM) and iron hydroxide corrosion products...
| Main Authors: | , , , , , |
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| Format: | Journal Article |
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Elsevier BV
2012
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| Online Access: | http://hdl.handle.net/20.500.11937/32855 |
| _version_ | 1848753779513491456 |
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| author | Zhan, Weixi Sathasivan, A. Joll, Cynthia Wai, G. Heitz, Anna Kristiana, Ina |
| author_facet | Zhan, Weixi Sathasivan, A. Joll, Cynthia Wai, G. Heitz, Anna Kristiana, Ina |
| author_sort | Zhan, Weixi |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | The fate of trace concentrations of cupric sulfate (<0.4 mg/L) dosed into chloraminated distribution systems to inhibit nitrification has been shown in this study to be controlled by at least two crucial factors: the character of natural organic matter (NOM) and iron hydroxide corrosion products present at low concentrations (<2 mg/L). This research quantified the removal of Cu(II) ions added into waters containing trace Fe(OH)3 flocs and the effect of NOM of different character on this removal. The dominant dissolved copper species in NOM-containing waters were found to be Cu(II)–NOM complexes. Both intramolecular chelation and intermolecular complexation can occur, with the latter occurring preferentially and resulting in the aggregation of smaller organic molecules to form larger molecules. The presence of ferric hydroxide flocs when Cu(II) ions were added into NOM-containing waters was shown to result in removal of Cu(II) ions, presumably as Cu(II)–NOM complexes. This removal was through adsorption processes obeying Freundlich isotherms, although the presence of larger NOM molecules and heterogeneous copper species (e.g. Cu(OH)2(s) and CuO(s)) appeared to shield smaller Cu(II)–NOM complexes from adsorption to some extent. For the strategy of inhibition of nitrification in distribution systems by the addition of Cu(II) ions, complexation of Cu(II) ions by NOM and adsorption of Cu(II)–NOM complexes by ferric hydroxide flocs released from pipe walls pose significant operational challenges to maintaining the concentration of Cu(II) ions through the distribution system. |
| first_indexed | 2025-11-14T08:29:56Z |
| format | Journal Article |
| id | curtin-20.500.11937-32855 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T08:29:56Z |
| publishDate | 2012 |
| publisher | Elsevier BV |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-328552019-02-19T04:28:02Z Impact of NOM character on copper adsorption by trace ferric hydroxide from iron corrosion in water supply system Zhan, Weixi Sathasivan, A. Joll, Cynthia Wai, G. Heitz, Anna Kristiana, Ina Adsorption isotherm Nitrification NOM Corrosion Adsorption Chloramine Copper Inhibition Distribution system The fate of trace concentrations of cupric sulfate (<0.4 mg/L) dosed into chloraminated distribution systems to inhibit nitrification has been shown in this study to be controlled by at least two crucial factors: the character of natural organic matter (NOM) and iron hydroxide corrosion products present at low concentrations (<2 mg/L). This research quantified the removal of Cu(II) ions added into waters containing trace Fe(OH)3 flocs and the effect of NOM of different character on this removal. The dominant dissolved copper species in NOM-containing waters were found to be Cu(II)–NOM complexes. Both intramolecular chelation and intermolecular complexation can occur, with the latter occurring preferentially and resulting in the aggregation of smaller organic molecules to form larger molecules. The presence of ferric hydroxide flocs when Cu(II) ions were added into NOM-containing waters was shown to result in removal of Cu(II) ions, presumably as Cu(II)–NOM complexes. This removal was through adsorption processes obeying Freundlich isotherms, although the presence of larger NOM molecules and heterogeneous copper species (e.g. Cu(OH)2(s) and CuO(s)) appeared to shield smaller Cu(II)–NOM complexes from adsorption to some extent. For the strategy of inhibition of nitrification in distribution systems by the addition of Cu(II) ions, complexation of Cu(II) ions by NOM and adsorption of Cu(II)–NOM complexes by ferric hydroxide flocs released from pipe walls pose significant operational challenges to maintaining the concentration of Cu(II) ions through the distribution system. 2012 Journal Article http://hdl.handle.net/20.500.11937/32855 10.1016/j.cej.2012.06.018 Elsevier BV fulltext |
| spellingShingle | Adsorption isotherm Nitrification NOM Corrosion Adsorption Chloramine Copper Inhibition Distribution system Zhan, Weixi Sathasivan, A. Joll, Cynthia Wai, G. Heitz, Anna Kristiana, Ina Impact of NOM character on copper adsorption by trace ferric hydroxide from iron corrosion in water supply system |
| title | Impact of NOM character on copper adsorption by trace ferric hydroxide from iron corrosion in water supply system |
| title_full | Impact of NOM character on copper adsorption by trace ferric hydroxide from iron corrosion in water supply system |
| title_fullStr | Impact of NOM character on copper adsorption by trace ferric hydroxide from iron corrosion in water supply system |
| title_full_unstemmed | Impact of NOM character on copper adsorption by trace ferric hydroxide from iron corrosion in water supply system |
| title_short | Impact of NOM character on copper adsorption by trace ferric hydroxide from iron corrosion in water supply system |
| title_sort | impact of nom character on copper adsorption by trace ferric hydroxide from iron corrosion in water supply system |
| topic | Adsorption isotherm Nitrification NOM Corrosion Adsorption Chloramine Copper Inhibition Distribution system |
| url | http://hdl.handle.net/20.500.11937/32855 |