Using Indicator Chemicals and Online Surrogates to Manage the Chemical Risk of Recycled Water

The Water Corporation of Western Australia’s Groundwater Replenishment Trial (GWRT) has recently tested a new approach for monitoring reverse osmosis (RO) treatment performance using a suite of treatment performance indicator (TPI) chemicals and two online surrogate parameters, conductivity and tota...

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Main Authors: Linge, Kathryn, Liew, Deborah, Edwards, B., Blair, P., Trolio, R., Cadee, K., Charrois, Jeffrey
Format: Journal Article
Published: Australian Water Association 2014
Subjects:
Online Access:http://digitaledition.awa.asn.au/?xml=Water_Journal_Secure&iid=101763#folio=78
http://hdl.handle.net/20.500.11937/32275
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author Linge, Kathryn
Liew, Deborah
Edwards, B.
Blair, P.
Trolio, R.
Cadee, K.
Charrois, Jeffrey
author_facet Linge, Kathryn
Liew, Deborah
Edwards, B.
Blair, P.
Trolio, R.
Cadee, K.
Charrois, Jeffrey
author_sort Linge, Kathryn
building Curtin Institutional Repository
collection Online Access
description The Water Corporation of Western Australia’s Groundwater Replenishment Trial (GWRT) has recently tested a new approach for monitoring reverse osmosis (RO) treatment performance using a suite of treatment performance indicator (TPI) chemicals and two online surrogate parameters, conductivity and total organic carbon. It was intended that TPIs would provide a conservative assessment of the removal of unmonitored chemicals with similar physicochemical characteristics. However, while operational and surrogate parameters indicated good RO performance, the calculated removal efficiency of many TPI failed to meet removal targets. External factors, including analytical method uncertainty, low feed concentration, and in some case the potential for chemicals to form within the treatment process, were found to significantly affect calculated removal. It was recommended that RO treatment performance monitoring should focus on surrogate parameters that can be measured online, as they provide immediate feedback that can be linked to variation in plant performance. In contrast, a set of chemical indicators chosen to consider health risks posed by a broad array of chemical classes proved valuable in demonstrating the ongoing safety of the recycled water.
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format Journal Article
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institution Curtin University Malaysia
institution_category Local University
last_indexed 2025-11-14T08:27:20Z
publishDate 2014
publisher Australian Water Association
recordtype eprints
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spelling curtin-20.500.11937-322752017-01-30T13:30:08Z Using Indicator Chemicals and Online Surrogates to Manage the Chemical Risk of Recycled Water Linge, Kathryn Liew, Deborah Edwards, B. Blair, P. Trolio, R. Cadee, K. Charrois, Jeffrey groundwater replenishment treatment performance indicator (TPI) Chemical risk reverse osmosis The Water Corporation of Western Australia’s Groundwater Replenishment Trial (GWRT) has recently tested a new approach for monitoring reverse osmosis (RO) treatment performance using a suite of treatment performance indicator (TPI) chemicals and two online surrogate parameters, conductivity and total organic carbon. It was intended that TPIs would provide a conservative assessment of the removal of unmonitored chemicals with similar physicochemical characteristics. However, while operational and surrogate parameters indicated good RO performance, the calculated removal efficiency of many TPI failed to meet removal targets. External factors, including analytical method uncertainty, low feed concentration, and in some case the potential for chemicals to form within the treatment process, were found to significantly affect calculated removal. It was recommended that RO treatment performance monitoring should focus on surrogate parameters that can be measured online, as they provide immediate feedback that can be linked to variation in plant performance. In contrast, a set of chemical indicators chosen to consider health risks posed by a broad array of chemical classes proved valuable in demonstrating the ongoing safety of the recycled water. 2014 Journal Article http://hdl.handle.net/20.500.11937/32275 http://digitaledition.awa.asn.au/?xml=Water_Journal_Secure&iid=101763#folio=78 Australian Water Association fulltext
spellingShingle groundwater replenishment
treatment performance indicator (TPI)
Chemical risk
reverse osmosis
Linge, Kathryn
Liew, Deborah
Edwards, B.
Blair, P.
Trolio, R.
Cadee, K.
Charrois, Jeffrey
Using Indicator Chemicals and Online Surrogates to Manage the Chemical Risk of Recycled Water
title Using Indicator Chemicals and Online Surrogates to Manage the Chemical Risk of Recycled Water
title_full Using Indicator Chemicals and Online Surrogates to Manage the Chemical Risk of Recycled Water
title_fullStr Using Indicator Chemicals and Online Surrogates to Manage the Chemical Risk of Recycled Water
title_full_unstemmed Using Indicator Chemicals and Online Surrogates to Manage the Chemical Risk of Recycled Water
title_short Using Indicator Chemicals and Online Surrogates to Manage the Chemical Risk of Recycled Water
title_sort using indicator chemicals and online surrogates to manage the chemical risk of recycled water
topic groundwater replenishment
treatment performance indicator (TPI)
Chemical risk
reverse osmosis
url http://digitaledition.awa.asn.au/?xml=Water_Journal_Secure&iid=101763#folio=78
http://hdl.handle.net/20.500.11937/32275