Flow Dependence of Carbon Dioxide Corrosion Using Short Electrodes by Jet Impingement

The jet impingement technique is a valuable methodology for the evaluation of carbon dioxide corrosion and inhibition under high flow velocities. This technique commonly employs short electrodes that remain within a region of the developing diffusion boundary layer induced by the reactively corrodin...

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Main Authors: John, Doug, Kinsella, Brian, Bailey, Stuart, De Marco, Roland
Format: Journal Article
Published: NACE International 2009
Subjects:
Online Access:http://hdl.handle.net/20.500.11937/32159
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author John, Doug
Kinsella, Brian
Bailey, Stuart
De Marco, Roland
author_facet John, Doug
Kinsella, Brian
Bailey, Stuart
De Marco, Roland
author_sort John, Doug
building Curtin Institutional Repository
collection Online Access
description The jet impingement technique is a valuable methodology for the evaluation of carbon dioxide corrosion and inhibition under high flow velocities. This technique commonly employs short electrodes that remain within a region of the developing diffusion boundary layer induced by the reactively corroding surface. The employment of such electrodes has been associated with the poor correlation of corrosion rates determined from field and laboratory measurements by various apparatus. This paper presents an investigation into the flow relationship of the carbon dioxide corrosion mechanism in non-scaling synthetic brine solutions at 30 C with a carbon dioxide partial pressure of 1.88 bar. The effect of the developing diffusion boundary layer on the corrosion rate and its dependence on the flow velocity is investigated by jet impingement using dissimilar electrode lengths in the flow direction.It is shown that the measured corrosion rate is dependent on the state of development of the diffusion boundary layer with a relationship that is contrary to the average rate of mass transfer. A more developed diffusion boundary layer exhibits a greater rate of carbon dioxide corrosion at a lower average mass transfer than in a developing diffusion boundary layer with a higher average mass transfer. This phenomenon illustrates an antagonistic effect of the diffusion boundary layer on the mechanism of carbon dioxide corrosion that is likely to strongly influence the correlation of corrosion rates obtained using various laboratory apparatus and field applications.
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spelling curtin-20.500.11937-321592017-01-30T13:29:32Z Flow Dependence of Carbon Dioxide Corrosion Using Short Electrodes by Jet Impingement John, Doug Kinsella, Brian Bailey, Stuart De Marco, Roland jet impingement flow dependence mass transfer entry length Carbon dioxide corrosion The jet impingement technique is a valuable methodology for the evaluation of carbon dioxide corrosion and inhibition under high flow velocities. This technique commonly employs short electrodes that remain within a region of the developing diffusion boundary layer induced by the reactively corroding surface. The employment of such electrodes has been associated with the poor correlation of corrosion rates determined from field and laboratory measurements by various apparatus. This paper presents an investigation into the flow relationship of the carbon dioxide corrosion mechanism in non-scaling synthetic brine solutions at 30 C with a carbon dioxide partial pressure of 1.88 bar. The effect of the developing diffusion boundary layer on the corrosion rate and its dependence on the flow velocity is investigated by jet impingement using dissimilar electrode lengths in the flow direction.It is shown that the measured corrosion rate is dependent on the state of development of the diffusion boundary layer with a relationship that is contrary to the average rate of mass transfer. A more developed diffusion boundary layer exhibits a greater rate of carbon dioxide corrosion at a lower average mass transfer than in a developing diffusion boundary layer with a higher average mass transfer. This phenomenon illustrates an antagonistic effect of the diffusion boundary layer on the mechanism of carbon dioxide corrosion that is likely to strongly influence the correlation of corrosion rates obtained using various laboratory apparatus and field applications. 2009 Journal Article http://hdl.handle.net/20.500.11937/32159 NACE International fulltext
spellingShingle jet impingement
flow dependence
mass transfer entry length
Carbon dioxide corrosion
John, Doug
Kinsella, Brian
Bailey, Stuart
De Marco, Roland
Flow Dependence of Carbon Dioxide Corrosion Using Short Electrodes by Jet Impingement
title Flow Dependence of Carbon Dioxide Corrosion Using Short Electrodes by Jet Impingement
title_full Flow Dependence of Carbon Dioxide Corrosion Using Short Electrodes by Jet Impingement
title_fullStr Flow Dependence of Carbon Dioxide Corrosion Using Short Electrodes by Jet Impingement
title_full_unstemmed Flow Dependence of Carbon Dioxide Corrosion Using Short Electrodes by Jet Impingement
title_short Flow Dependence of Carbon Dioxide Corrosion Using Short Electrodes by Jet Impingement
title_sort flow dependence of carbon dioxide corrosion using short electrodes by jet impingement
topic jet impingement
flow dependence
mass transfer entry length
Carbon dioxide corrosion
url http://hdl.handle.net/20.500.11937/32159