First-order phase transition in the Li2B12H12 system

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First-order phase transition in the Li2B12H12 system

The thermal decomposition of anhydrous Pa[3 with combining macron] Li2B12H12 was studied in situ by high resolution synchrotron X-ray diffraction. A first-order phase transition can be observed at 355 °C where the unit cell volume expands by ca. 8.7%. The expanded β-Li2B12H12 polymorph simultaneousl...

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Bibliographic Details
Main Authors:	Paskevicius, Mark, Pitt, M., Brown, David, Sheppard, Drew, Chumphongphan, Somwan, Buckley, Craig
Format:	Journal Article
Published:	R S C Publications 2013
Online Access:	http://hdl.handle.net/20.500.11937/31525

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