The complex hydrothermal history of granitic rocks: Multiple feldspar replacement reactions under subsolidus conditions

Recurring subsolidus re-equilibration of granitic feldspars induced by fluid infiltration events provides a record of fluid-rock interactions that affect large volumes of the Earth's continental crust. This has a direct bearing on the interpretation of the present-day granitic rock mineralogy a...

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Main Authors: Plümper, O., Putnis, Andrew
Format: Journal Article
Published: Oxford University Press 2009
Online Access:http://hdl.handle.net/20.500.11937/31418
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author Plümper, O.
Putnis, Andrew
author_facet Plümper, O.
Putnis, Andrew
author_sort Plümper, O.
building Curtin Institutional Repository
collection Online Access
description Recurring subsolidus re-equilibration of granitic feldspars induced by fluid infiltration events provides a record of fluid-rock interactions that affect large volumes of the Earth's continental crust. This has a direct bearing on the interpretation of the present-day granitic rock mineralogy and geochemistry. We examine Palaeoproterozoic grey and red-stained granitoids from the Simpevarp and Laxemar areas in SE Sweden, particularly focusing on consecutive feldspar replacement reactions, to provide an in-depth understanding of subsolidus re-equilibration of granitic rocks with hydrothermal fluids. The apparently most unaltered grey granitoids contain highly porous oligoclase grains that enclose crystallographically continuous microcline relicts. This texture suggests that the oligoclase is already secondary and may be a replacement product of original microcline. Oligoclase is progressively replaced by albite (~An9) along polysynthetic twinning and intragranular fractures. The features of this replacement are characteristic of a dissolution-reprecipitation mechanism. Fine-grained mica (sericite) is closely associated with the albite porosity within micron-sized pores observable with scanning electron microscopy as well as in nanopores imaged with transmission electron microscopy. The reddening phenomenon in the vicinity of fractures is contemporaneously related to the K-feldspathization of sericite, which is restricted to the altered oligoclase. Submicron size hematite precipitation within orthoclase pores at the replacement front results in the red coloration. The complex associations between the fluid-feldspar reactions indicate that the replacement reactions may be due to sequential fluid infiltration events and that the granitoids have undergone extensive subsolidus re-equilibration, changing the original magmatic mineralogy. Therefore, the effects of large-scale re-equilibrations of granitic rocks through hydrothermal convection systems should be more closely considered. © The Author 2009. Published by Oxford University Press. All rights reserved.
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spelling curtin-20.500.11937-314182017-09-13T15:19:34Z The complex hydrothermal history of granitic rocks: Multiple feldspar replacement reactions under subsolidus conditions Plümper, O. Putnis, Andrew Recurring subsolidus re-equilibration of granitic feldspars induced by fluid infiltration events provides a record of fluid-rock interactions that affect large volumes of the Earth's continental crust. This has a direct bearing on the interpretation of the present-day granitic rock mineralogy and geochemistry. We examine Palaeoproterozoic grey and red-stained granitoids from the Simpevarp and Laxemar areas in SE Sweden, particularly focusing on consecutive feldspar replacement reactions, to provide an in-depth understanding of subsolidus re-equilibration of granitic rocks with hydrothermal fluids. The apparently most unaltered grey granitoids contain highly porous oligoclase grains that enclose crystallographically continuous microcline relicts. This texture suggests that the oligoclase is already secondary and may be a replacement product of original microcline. Oligoclase is progressively replaced by albite (~An9) along polysynthetic twinning and intragranular fractures. The features of this replacement are characteristic of a dissolution-reprecipitation mechanism. Fine-grained mica (sericite) is closely associated with the albite porosity within micron-sized pores observable with scanning electron microscopy as well as in nanopores imaged with transmission electron microscopy. The reddening phenomenon in the vicinity of fractures is contemporaneously related to the K-feldspathization of sericite, which is restricted to the altered oligoclase. Submicron size hematite precipitation within orthoclase pores at the replacement front results in the red coloration. The complex associations between the fluid-feldspar reactions indicate that the replacement reactions may be due to sequential fluid infiltration events and that the granitoids have undergone extensive subsolidus re-equilibration, changing the original magmatic mineralogy. Therefore, the effects of large-scale re-equilibrations of granitic rocks through hydrothermal convection systems should be more closely considered. © The Author 2009. Published by Oxford University Press. All rights reserved. 2009 Journal Article http://hdl.handle.net/20.500.11937/31418 10.1093/petrology/egp028 Oxford University Press unknown
spellingShingle Plümper, O.
Putnis, Andrew
The complex hydrothermal history of granitic rocks: Multiple feldspar replacement reactions under subsolidus conditions
title The complex hydrothermal history of granitic rocks: Multiple feldspar replacement reactions under subsolidus conditions
title_full The complex hydrothermal history of granitic rocks: Multiple feldspar replacement reactions under subsolidus conditions
title_fullStr The complex hydrothermal history of granitic rocks: Multiple feldspar replacement reactions under subsolidus conditions
title_full_unstemmed The complex hydrothermal history of granitic rocks: Multiple feldspar replacement reactions under subsolidus conditions
title_short The complex hydrothermal history of granitic rocks: Multiple feldspar replacement reactions under subsolidus conditions
title_sort complex hydrothermal history of granitic rocks: multiple feldspar replacement reactions under subsolidus conditions
url http://hdl.handle.net/20.500.11937/31418