A lanthanum picrate complex of a 1,2-bisamide substituted calix[4]arene
The synthesis and structural characterization of a lanthanum picrate complex of the proximally-substituted calix[4]arene bisamide, 5,11,17,23-tetra-tert-butyl-25,26- bis(diethylcarbamoylmethoxy)-27,28-dihydroxycalix[4] arene (L), is reported. The complex is formulated as [La(L-H)(picrate)2]2.75CH2Cl...
| Main Authors: | , , , |
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| Format: | Journal Article |
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Springer Netherlands
2015
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| Online Access: | http://hdl.handle.net/20.500.11937/30447 |
| _version_ | 1848753091526000640 |
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| author | McIldowie, Matthew Skelton, B. Mocerino, Mauro Ogden, Mark |
| author_facet | McIldowie, Matthew Skelton, B. Mocerino, Mauro Ogden, Mark |
| author_sort | McIldowie, Matthew |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | The synthesis and structural characterization of a lanthanum picrate complex of the proximally-substituted calix[4]arene bisamide, 5,11,17,23-tetra-tert-butyl-25,26- bis(diethylcarbamoylmethoxy)-27,28-dihydroxycalix[4] arene (L), is reported. The complex is formulated as [La(L-H)(picrate)2]2.75CH2Cl2 and crystallises with two inequivalent metal complexes in the unit cell. The differing dispositions of the picrate anions in the two complexes suggest that intramolecular interactions between the aromatic rings of the picrate and calixarene are less significant than the forces involved in the crystal packing of the complexes. |
| first_indexed | 2025-11-14T08:19:00Z |
| format | Journal Article |
| id | curtin-20.500.11937-30447 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T08:19:00Z |
| publishDate | 2015 |
| publisher | Springer Netherlands |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-304472019-02-19T05:36:14Z A lanthanum picrate complex of a 1,2-bisamide substituted calix[4]arene McIldowie, Matthew Skelton, B. Mocerino, Mauro Ogden, Mark Lanthanide Calixarene Crystal structure Picrate The synthesis and structural characterization of a lanthanum picrate complex of the proximally-substituted calix[4]arene bisamide, 5,11,17,23-tetra-tert-butyl-25,26- bis(diethylcarbamoylmethoxy)-27,28-dihydroxycalix[4] arene (L), is reported. The complex is formulated as [La(L-H)(picrate)2]2.75CH2Cl2 and crystallises with two inequivalent metal complexes in the unit cell. The differing dispositions of the picrate anions in the two complexes suggest that intramolecular interactions between the aromatic rings of the picrate and calixarene are less significant than the forces involved in the crystal packing of the complexes. 2015 Journal Article http://hdl.handle.net/20.500.11937/30447 10.1007/s10847-015-0475-1 Springer Netherlands fulltext |
| spellingShingle | Lanthanide Calixarene Crystal structure Picrate McIldowie, Matthew Skelton, B. Mocerino, Mauro Ogden, Mark A lanthanum picrate complex of a 1,2-bisamide substituted calix[4]arene |
| title | A lanthanum picrate complex of a 1,2-bisamide substituted calix[4]arene |
| title_full | A lanthanum picrate complex of a 1,2-bisamide substituted calix[4]arene |
| title_fullStr | A lanthanum picrate complex of a 1,2-bisamide substituted calix[4]arene |
| title_full_unstemmed | A lanthanum picrate complex of a 1,2-bisamide substituted calix[4]arene |
| title_short | A lanthanum picrate complex of a 1,2-bisamide substituted calix[4]arene |
| title_sort | lanthanum picrate complex of a 1,2-bisamide substituted calix[4]arene |
| topic | Lanthanide Calixarene Crystal structure Picrate |
| url | http://hdl.handle.net/20.500.11937/30447 |