Carbon aerogels from acetic acid catalysed resorcinol–furfural using supercritical drying for hydrogen storage
Organic aerogels were derived from aceticacidcatalysedresorcinol and furfural and then dried directly in supercriticalcarbon dioxide without the use of a solvent exchange process. These aerogels were further carbonised in nitrogen and activated in CO2 in order to obtain their corresponding carbonaer...
| Main Authors: | , , , |
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| Format: | Journal Article |
| Published: |
Elsevier BV
2011
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| Online Access: | http://hdl.handle.net/20.500.11937/29020 |
| _version_ | 1848752691474333696 |
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| author | Tian, Hu-Yong Buckley, Craig Paskevicius, Mark Wang, Shaobin |
| author_facet | Tian, Hu-Yong Buckley, Craig Paskevicius, Mark Wang, Shaobin |
| author_sort | Tian, Hu-Yong |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | Organic aerogels were derived from aceticacidcatalysedresorcinol and furfural and then dried directly in supercriticalcarbon dioxide without the use of a solvent exchange process. These aerogels were further carbonised in nitrogen and activated in CO2 in order to obtain their corresponding carbonaerogels. The carbonaerogels prepared by this method had a greater proportion of micropores in addition to a much shorter preparation time (on the order of days) than those prepared by other studies. The effect of different drying techniques on the microstructure of the wet gels was investigated by nitrogen adsorption at cryogenic liquid nitrogen temperature. Nitrogen adsorption at 77 K allowed the determination of surface areas and pore volumes, further analysed by the Dubinin–Radushkevich model and density functional theory model. The surface area and micropore volume of carbonaerogels prepared by this method increased by 19% and 12%, and accordingly, hydrogen uptake capacity was increased by 10% from 4.9 ± 0.2 wt.% to 5.4 ± 0.3 wt.% at 4.6 MPa and 77 K. |
| first_indexed | 2025-11-14T08:12:39Z |
| format | Journal Article |
| id | curtin-20.500.11937-29020 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T08:12:39Z |
| publishDate | 2011 |
| publisher | Elsevier BV |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-290202017-09-13T16:08:34Z Carbon aerogels from acetic acid catalysed resorcinol–furfural using supercritical drying for hydrogen storage Tian, Hu-Yong Buckley, Craig Paskevicius, Mark Wang, Shaobin Organic aerogels were derived from aceticacidcatalysedresorcinol and furfural and then dried directly in supercriticalcarbon dioxide without the use of a solvent exchange process. These aerogels were further carbonised in nitrogen and activated in CO2 in order to obtain their corresponding carbonaerogels. The carbonaerogels prepared by this method had a greater proportion of micropores in addition to a much shorter preparation time (on the order of days) than those prepared by other studies. The effect of different drying techniques on the microstructure of the wet gels was investigated by nitrogen adsorption at cryogenic liquid nitrogen temperature. Nitrogen adsorption at 77 K allowed the determination of surface areas and pore volumes, further analysed by the Dubinin–Radushkevich model and density functional theory model. The surface area and micropore volume of carbonaerogels prepared by this method increased by 19% and 12%, and accordingly, hydrogen uptake capacity was increased by 10% from 4.9 ± 0.2 wt.% to 5.4 ± 0.3 wt.% at 4.6 MPa and 77 K. 2011 Journal Article http://hdl.handle.net/20.500.11937/29020 10.1016/j.supflu.2010.10.028 Elsevier BV restricted |
| spellingShingle | Tian, Hu-Yong Buckley, Craig Paskevicius, Mark Wang, Shaobin Carbon aerogels from acetic acid catalysed resorcinol–furfural using supercritical drying for hydrogen storage |
| title | Carbon aerogels from acetic acid catalysed resorcinol–furfural using supercritical drying for hydrogen storage |
| title_full | Carbon aerogels from acetic acid catalysed resorcinol–furfural using supercritical drying for hydrogen storage |
| title_fullStr | Carbon aerogels from acetic acid catalysed resorcinol–furfural using supercritical drying for hydrogen storage |
| title_full_unstemmed | Carbon aerogels from acetic acid catalysed resorcinol–furfural using supercritical drying for hydrogen storage |
| title_short | Carbon aerogels from acetic acid catalysed resorcinol–furfural using supercritical drying for hydrogen storage |
| title_sort | carbon aerogels from acetic acid catalysed resorcinol–furfural using supercritical drying for hydrogen storage |
| url | http://hdl.handle.net/20.500.11937/29020 |