Structural characterisation and photophysical properties of lanthanoid complexes of a tetra-amide functionalised calix[4]arene
Lanthanoid complexes of a tetra-amide substituted calix[4]arene in the cone conformation are characterised by single crystal X-ray structure determination. The structural analysis shows that the metal ions are coordinated to the calixarene through the eight O donor atoms, along with one aqua ligand...
| Main Authors: | , , , |
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| Format: | Journal Article |
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Taylor and Francis Ltd
2016
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| Online Access: | http://hdl.handle.net/20.500.11937/28499 |
| _version_ | 1848752553686204416 |
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| author | Driscoll, C. Skelton, B. Massi, Massimiliano Ogden, Mark |
| author_facet | Driscoll, C. Skelton, B. Massi, Massimiliano Ogden, Mark |
| author_sort | Driscoll, C. |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | Lanthanoid complexes of a tetra-amide substituted calix[4]arene in the cone conformation are characterised by single crystal X-ray structure determination. The structural analysis shows that the metal ions are coordinated to the calixarene through the eight O donor atoms, along with one aqua ligand which is located within the cavity of the calixarene. The calixarene ligand was covalently incorporated into a polymethylmethacrylate monolith through p-allyl functional groups, followed by loading with a range of lanthanoid cations giving rise to light-emitting materials. The emission from the hydrid materials was found to be comparable to the solution phase emission. |
| first_indexed | 2025-11-14T08:10:27Z |
| format | Journal Article |
| id | curtin-20.500.11937-28499 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T08:10:27Z |
| publishDate | 2016 |
| publisher | Taylor and Francis Ltd |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-284992017-09-13T15:20:56Z Structural characterisation and photophysical properties of lanthanoid complexes of a tetra-amide functionalised calix[4]arene Driscoll, C. Skelton, B. Massi, Massimiliano Ogden, Mark Lanthanoid complexes of a tetra-amide substituted calix[4]arene in the cone conformation are characterised by single crystal X-ray structure determination. The structural analysis shows that the metal ions are coordinated to the calixarene through the eight O donor atoms, along with one aqua ligand which is located within the cavity of the calixarene. The calixarene ligand was covalently incorporated into a polymethylmethacrylate monolith through p-allyl functional groups, followed by loading with a range of lanthanoid cations giving rise to light-emitting materials. The emission from the hydrid materials was found to be comparable to the solution phase emission. 2016 Journal Article http://hdl.handle.net/20.500.11937/28499 10.1080/10610278.2015.1136744 Taylor and Francis Ltd fulltext |
| spellingShingle | Driscoll, C. Skelton, B. Massi, Massimiliano Ogden, Mark Structural characterisation and photophysical properties of lanthanoid complexes of a tetra-amide functionalised calix[4]arene |
| title | Structural characterisation and photophysical properties of lanthanoid complexes of a tetra-amide functionalised calix[4]arene |
| title_full | Structural characterisation and photophysical properties of lanthanoid complexes of a tetra-amide functionalised calix[4]arene |
| title_fullStr | Structural characterisation and photophysical properties of lanthanoid complexes of a tetra-amide functionalised calix[4]arene |
| title_full_unstemmed | Structural characterisation and photophysical properties of lanthanoid complexes of a tetra-amide functionalised calix[4]arene |
| title_short | Structural characterisation and photophysical properties of lanthanoid complexes of a tetra-amide functionalised calix[4]arene |
| title_sort | structural characterisation and photophysical properties of lanthanoid complexes of a tetra-amide functionalised calix[4]arene |
| url | http://hdl.handle.net/20.500.11937/28499 |