Water soluble lanthanoid benzoate complexes for the kinetic separation of cis/trans-limonene oxide

QR Code

Water soluble lanthanoid benzoate complexes for the kinetic separation of cis/trans-limonene oxide

A new class of water soluble, environmentally friendly, lanthanoid 3,5-diacetamidobenzoate complexes (Ln = La, Gd, Yb) have been synthesized. The La and Gd complexes selectively catalyse hydrolysis of the cis-isomer of limonene oxide allowing for the separation of the trans-isomer (> 98:2 dr)...

Full description

Bibliographic Details
Main Authors:	Andrews, P., Blair, M., Fraser, B., Junk, P., Massi, Massimiliano, Tuck, K.
Format:	Journal Article
Published:	PERGAMON-ELSEVIER SCIENCE LTD, THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND 2006
Subjects:	RESOLUTION ORGANIC-SYNTHESIS CATALYSIS LIGANDS EPOXIDES TRIFLATE
Online Access:	http://hdl.handle.net/20.500.11937/28389

Similar Items

A study of the formation and application of new chiral water soluble lanthanoid benzoates using real-time infrared spectroscopy
by: Andrews, P., et al.
Published: (2010)

Diol-functionalised benzoates as novel linkers for the formation of coordination polymers
by: Andrews, P., et al.
Published: (2007)

Direct determination of absolute configuration: a vibrational circular dichroism study on dimethyl-substituted phenyloxiranes synthesized by Shi epoxidation
by: Fristrup, P., et al.
Published: (2008)

Synthesis and structural characterisation of cationic, neutral and hydroxo-bridged lanthanoid (La, Gd, Ho, Yb, Y) bis 5-(2-pyridyl)tetrazolate complexes
by: Andrews, P., et al.
Published: (2007)

Variation of structural motifs in lanthanoid hydroxo clusters by ligand modification
by: Andrews, Philip, et al.
Published: (2013)

Functionalised beta-diketonate polynuclear lanthanoid hydroxo clusters: Synthesis, characterisation, and magnetic properties
by: Andrews, P., et al.
Published: (2009)

Formation of Ho-III Trinuclear Clusters and Gd-III Monodimensional Polymers Induced by ortho and para Regioisomers of Pyridyl-Functionalised beta-Diketones: Synthesis, Structure, and Magnetic Properties
by: Andrews, P., et al.
Published: (2009)

Iron(II) catalyzed hydrophosphination of isocyanates
by: Sharpe, Helen R., et al.
Published: (2017)

Synthesis and Characterisation of Mono- and Bidentate Alkoxybenzimidazolin-2-ylidene Palladium Complexes: Interesting Solution Behaviour and Application in Catalysis
by: Simpson, P., et al.
Published: (2011)

Multifunctional hybrid materials based on transparent poly(methyl methacrylate) reinforced by lanthanoid hydroxo clusters
by: Andrews, P., et al.
Published: (2010)

Lanthanoid tetrazole coordination complexes
by: Massi, Massimiliano, et al.
Published: (2018)

Luminescent Lanthanoid Calixarene Complexes and Materials
by: Massi, Massimiliano, et al.
Published: (2017)

trans–cis S-Benzyl dithiocarbazate
by: Shanmuga Sundara Raj, S., et al.
Published: (2000)

Synthesis of silica supported bimetallic oxide (NiCo) catalyst for CO2 methanation / Siti Aminah Md Ali
by: Md Ali, Siti Aminah
Published: (2018)

Synthesis, characterization, and reactivity of a uranium(VI) carbene imido oxo complex
by: Lu, Erli, et al.
Published: (2014)

Sterically demanding pincer ligands for transition metal chemistry
by: Albelwe, Bayan L.
Published: (2025)

Synthesis, characterization, and bioactivities of dithiocarbazate-Schiff base ligands and their metal complexes
by: Low, May Lee
Published: (2014)

Alkaline earth complexes of a sterically demanding guanidinate ligand
by: Moxey, Graeme J., et al.
Published: (2015)

Design, synthesis and applications of hydroxylmethyl-aryl phosphine oxides in phosphorus catalysis
by: Chapman, Charlotte Grace
Published: (2015)

Development of Magnesium Complexes for Heterofunctionalisation Catalysis
by: Barnes, Lydia
Published: (2024)

Nickel-catalysed enantioselective arylative cyclisations
by: Clarke, Christopher
Published: (2019)

Stereoselective nickel-catalysed arylative cyclisation reactions
by: Panchal, Heena
Published: (2019)

Measuring ligand concentration where it matters: Assessing the “micro pharmacokinetic/pharmacodynamics” of adenosine receptor ligands
by: Lochray, Jack
Published: (2022)

Geometric adventures with self-assembled metal-ligand coordination structures
by: Fan, Yucong
Published: (2024)

Lanthanoid Complexation by a Tris-Tetrazole-Functionalised Calix[4]arene
by: D'Alessio, D., et al.
Published: (2016)

Gelation of La(III) cations promoted by 5-(2-pyridyl) tetrazolate and water
by: Andrews, P., et al.
Published: (2006)

Luminescent lanthanoid complexes of a tetrazole-functionalised calix[4]arene
by: D’Alessio, Daniel, et al.
Published: (2012)

Synthesis and Complexation of a Bulky Silyl Phosphanide and Extended PNNNP Carbazole-based Ligand
by: Churchill, Olivia
Published: (2024)

Synthesis, characterization and biological activities of tridentate ons Schiff bases and their mixed-ligand metal complexes containing imidazole or benzimidazole
by: Mazlan, Nurul Ain
Published: (2014)

Lanthanoid complexes supported by retro-Claisen condensation products of ß-triketonates.
by: Abad Galán, L., et al.
Published: (2018)

Synthesis, characterization and catalytic activity of pall adium(ii)-l,3-bis[(4-chl orophenyl)methyl]-1- benzimidazolium bromide complex in heck reaction / Nina Natasha Md Sani
by: Md Sani, Nina Natasha
Published: (2017)

Characterization of Molybdenum-Vanadium Oxide Catalyst Prepared By Homogeneous Precipitation Method Using Urea Hydrolysis
by: Woi, Pei Meng
Published: (2007)

Catalytic oxidative dehydrogenation of propane by AMoVNbOx (A = Ni, Co, Pt) synthesised via impregnation method
by: Wong, Mei Sam
Published: (2013)

Quantitative gas chromatographic method for the analysis of cis and trans fatty acid in margarines
by: Jumat Salimon,, et al.
Published: (2014)

Structural characterisation and photophysical properties of lanthanoid complexes of a tetra-amide functionalised calix[4]arene
by: Driscoll, C., et al.
Published: (2016)

Hydrated Lanthanoid Complexes of 5-(2'-Pyridyl)tetrazole Formed in the Presence of Dimethyl Sulfoxide
by: D'Alessio, D., et al.
Published: (2012)

Supported nano-sized gold catalysts for selective reduction of 4,4'-dinitrostilbene-2,2'-disulfonic acid using different reductants
by: Chen, Y., et al.
Published: (2012)

1,4-addition of TMSCCl3to nitroalkenes: efficient reaction conditions and mechanistic understanding
by: Wu, Na, et al.
Published: (2014)

Lanthanoid “Bottlebrush” Clusters: Remarkably Elongated Metal-Oxo Core Structures with Controllable Lengths
by: D'Alessio, Daniel, et al.
Published: (2014)

Templated assembly of a µ6-CO32- dodecanuclear lanthanum dibenzoylmethanide hydroxido cluster with concomitant formation of phenylglyoxylate
by: Andrews, P., et al.
Published: (2007)

Cannot write session to /tmp/vufind_sessions/sess_j5vhhkcbahkkn46i2mc0l396vn