Thermal inkjet printing of thin-film electrolytes and buffering layers for solid oxide fuel cells with improved performance

In this study, we report the facile fabrication of thin-film yttria-stabilized zirconia (YSZ) electrolytes and Sm0.2Ce0.8O1.9 (SDC) buffering layers for solid oxide fuel cells (SOFCs) using a thermal inkjet printing technique. Stable YSZ and SDC inks with solids contents as high as 20 and 10 wt.%, r...

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Main Authors: Li, C., Shi, H., Ran, R., Su, C., Shao, Z.
Format: Journal Article
Published: Elsevier Ltd 2013
Subjects:
Online Access:http://hdl.handle.net/20.500.11937/28021
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author Li, C.
Shi, H.
Ran, R.
Su, C.
Shao, Z.
author_facet Li, C.
Shi, H.
Ran, R.
Su, C.
Shao, Z.
author_sort Li, C.
building Curtin Institutional Repository
collection Online Access
description In this study, we report the facile fabrication of thin-film yttria-stabilized zirconia (YSZ) electrolytes and Sm0.2Ce0.8O1.9 (SDC) buffering layers for solid oxide fuel cells (SOFCs) using a thermal inkjet printing technique. Stable YSZ and SDC inks with solids contents as high as 20 and 10 wt.%, respectively, were first prepared. One single printing typically resulted in an YSZ membrane with thickness of approximately 1.5 μm, and membranes with thicknesses varied from 1.5 to 7.5 μm were fabricated with multiple sequential printing. An as-fabricated cell with a La0.8Sr0.2MnO3 (LSM) cathode delivered a peak power density (PPD) of 860 mW cm−2 at 800 °C. The SDC layer prepared using the inkjet printing method exhibited enclosed pores and a rough surface, which was, however, ideal for its application as a buffering layer. A cell with a dense 7.5-μm-thick YSZ layer, a 2-μm-thick SDC buffering layer and a Ba0.5Sr0.5Co0.8Fe0.2O3−δ (BSCF) cathode was fabricated; this cell delivered a PPD of 1040 mW cm−2 at 750 °C and a high open circuit voltage (OCV) of approximately 1.10 V. The described technique provides a facile method for the fabrication of electrolytes for SOFCs with precise thickness control.
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institution Curtin University Malaysia
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publishDate 2013
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spelling curtin-20.500.11937-280212017-09-13T15:12:26Z Thermal inkjet printing of thin-film electrolytes and buffering layers for solid oxide fuel cells with improved performance Li, C. Shi, H. Ran, R. Su, C. Shao, Z. thin film inkjet printing solid oxide fuel cells buffering layer electrolyte In this study, we report the facile fabrication of thin-film yttria-stabilized zirconia (YSZ) electrolytes and Sm0.2Ce0.8O1.9 (SDC) buffering layers for solid oxide fuel cells (SOFCs) using a thermal inkjet printing technique. Stable YSZ and SDC inks with solids contents as high as 20 and 10 wt.%, respectively, were first prepared. One single printing typically resulted in an YSZ membrane with thickness of approximately 1.5 μm, and membranes with thicknesses varied from 1.5 to 7.5 μm were fabricated with multiple sequential printing. An as-fabricated cell with a La0.8Sr0.2MnO3 (LSM) cathode delivered a peak power density (PPD) of 860 mW cm−2 at 800 °C. The SDC layer prepared using the inkjet printing method exhibited enclosed pores and a rough surface, which was, however, ideal for its application as a buffering layer. A cell with a dense 7.5-μm-thick YSZ layer, a 2-μm-thick SDC buffering layer and a Ba0.5Sr0.5Co0.8Fe0.2O3−δ (BSCF) cathode was fabricated; this cell delivered a PPD of 1040 mW cm−2 at 750 °C and a high open circuit voltage (OCV) of approximately 1.10 V. The described technique provides a facile method for the fabrication of electrolytes for SOFCs with precise thickness control. 2013 Journal Article http://hdl.handle.net/20.500.11937/28021 10.1016/j.ijhydene.2013.05.025 Elsevier Ltd restricted
spellingShingle thin film
inkjet printing
solid oxide fuel cells
buffering layer
electrolyte
Li, C.
Shi, H.
Ran, R.
Su, C.
Shao, Z.
Thermal inkjet printing of thin-film electrolytes and buffering layers for solid oxide fuel cells with improved performance
title Thermal inkjet printing of thin-film electrolytes and buffering layers for solid oxide fuel cells with improved performance
title_full Thermal inkjet printing of thin-film electrolytes and buffering layers for solid oxide fuel cells with improved performance
title_fullStr Thermal inkjet printing of thin-film electrolytes and buffering layers for solid oxide fuel cells with improved performance
title_full_unstemmed Thermal inkjet printing of thin-film electrolytes and buffering layers for solid oxide fuel cells with improved performance
title_short Thermal inkjet printing of thin-film electrolytes and buffering layers for solid oxide fuel cells with improved performance
title_sort thermal inkjet printing of thin-film electrolytes and buffering layers for solid oxide fuel cells with improved performance
topic thin film
inkjet printing
solid oxide fuel cells
buffering layer
electrolyte
url http://hdl.handle.net/20.500.11937/28021