Pharmaceutical modulation of diffusion potentials at aqueous–aqueous boundaries under laminar flow conditions

In this work, the modulation of the diffusion potential formed at the microfluidic aqueous–aqueous boundary by a pharmaceutical substance is presented. Co-flowing aqueous streams in a microchannel were used to form the stable boundary between the streams. Measurement of the open circuit potential be...

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Main Authors: Collins, C., Strutwolf, J., Arrigan, Damien
Format: Journal Article
Published: Wiley-VCH Verlag 2011
Subjects:
Online Access:http://hdl.handle.net/20.500.11937/2782
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author Collins, C.
Strutwolf, J.
Arrigan, Damien
author_facet Collins, C.
Strutwolf, J.
Arrigan, Damien
author_sort Collins, C.
building Curtin Institutional Repository
collection Online Access
description In this work, the modulation of the diffusion potential formed at the microfluidic aqueous–aqueous boundary by a pharmaceutical substance is presented. Co-flowing aqueous streams in a microchannel were used to form the stable boundary between the streams. Measurement of the open circuit potential between two silver/silver chloride electrodes enabled the diffusion potential at the boundary to be determined, which is concentration dependent. Experimental results for protonated propranolol as well as tetrapropylammonium are presented. This concept may be useful as a strategy for the detection of drug substances.
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institution Curtin University Malaysia
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publishDate 2011
publisher Wiley-VCH Verlag
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spelling curtin-20.500.11937-27822017-09-13T16:02:17Z Pharmaceutical modulation of diffusion potentials at aqueous–aqueous boundaries under laminar flow conditions Collins, C. Strutwolf, J. Arrigan, Damien Microfluidic Propranolol Liquid junction Potentiometry Diffusion potential In this work, the modulation of the diffusion potential formed at the microfluidic aqueous–aqueous boundary by a pharmaceutical substance is presented. Co-flowing aqueous streams in a microchannel were used to form the stable boundary between the streams. Measurement of the open circuit potential between two silver/silver chloride electrodes enabled the diffusion potential at the boundary to be determined, which is concentration dependent. Experimental results for protonated propranolol as well as tetrapropylammonium are presented. This concept may be useful as a strategy for the detection of drug substances. 2011 Journal Article http://hdl.handle.net/20.500.11937/2782 10.1002/elps.201000299 Wiley-VCH Verlag restricted
spellingShingle Microfluidic
Propranolol
Liquid junction
Potentiometry
Diffusion potential
Collins, C.
Strutwolf, J.
Arrigan, Damien
Pharmaceutical modulation of diffusion potentials at aqueous–aqueous boundaries under laminar flow conditions
title Pharmaceutical modulation of diffusion potentials at aqueous–aqueous boundaries under laminar flow conditions
title_full Pharmaceutical modulation of diffusion potentials at aqueous–aqueous boundaries under laminar flow conditions
title_fullStr Pharmaceutical modulation of diffusion potentials at aqueous–aqueous boundaries under laminar flow conditions
title_full_unstemmed Pharmaceutical modulation of diffusion potentials at aqueous–aqueous boundaries under laminar flow conditions
title_short Pharmaceutical modulation of diffusion potentials at aqueous–aqueous boundaries under laminar flow conditions
title_sort pharmaceutical modulation of diffusion potentials at aqueous–aqueous boundaries under laminar flow conditions
topic Microfluidic
Propranolol
Liquid junction
Potentiometry
Diffusion potential
url http://hdl.handle.net/20.500.11937/2782