Fabrication, characterization, and photocatalytic property of alpha-Fe2O3/graphene oxide composite

Spindle-shaped microstructure of alpha-Fe2O3 was successfully synthesized by a simple hydrothermal method. The alpha-Fe2O3/graphene oxide (GO) composites was prepared using a modified Hummers’ strategy. The properties of the samples were systematically investigated by X-ray powder diffraction (XRD),...

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Main Authors: Li, H., Zhao, Q., Li, X., Zhu, Z., Tade, Moses, Liu, Shaomin
Format: Journal Article
Published: Springer Netherlands 2013
Subjects:
Online Access:http://hdl.handle.net/20.500.11937/27315
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author Li, H.
Zhao, Q.
Li, X.
Zhu, Z.
Tade, Moses
Liu, Shaomin
author_facet Li, H.
Zhao, Q.
Li, X.
Zhu, Z.
Tade, Moses
Liu, Shaomin
author_sort Li, H.
building Curtin Institutional Repository
collection Online Access
description Spindle-shaped microstructure of alpha-Fe2O3 was successfully synthesized by a simple hydrothermal method. The alpha-Fe2O3/graphene oxide (GO) composites was prepared using a modified Hummers’ strategy. The properties of the samples were systematically investigated by X-ray powder diffraction (XRD), UV–Vis diffuse reflectance spectrophotometer, transmission electron microscope, atomic force microscope, X-ray photoelectron spectroscopy, and Raman spectroscopy (Raman) techniques. GO nanosheets act as supporting materials for anchoring the alpha-Fe2O3 particles. The average crystallite sizes of the alpha-Fe2O3 and alpha-Fe2O3/GO samples are ca. 27 and 24 nm, respectively. The possible growth of alpha-Fe2O3onto GO layers led to a higher absorbance capacity for visible light by a-Fe2O3/GO than alpha-Fe2O3 composite. The photocatalytic degradation of toluene over the alpha-Fe2O3 and alpha-Fe2O3/GO samples under xenon-lamp irradiation was comparatively studied by in situ FTIR technique. The results indicate that the alpha-Fe2O3/GO sample synthesized exhibited a higher capacity for the degradation of toluene. The composite of alpha-Fe2O3/GO could be promisingly applied in photo-driven air purification.
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institution Curtin University Malaysia
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publishDate 2013
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spelling curtin-20.500.11937-273152017-09-13T15:32:02Z Fabrication, characterization, and photocatalytic property of alpha-Fe2O3/graphene oxide composite Li, H. Zhao, Q. Li, X. Zhu, Z. Tade, Moses Liu, Shaomin In situ FTIR Graphene oxide alpha-Fe2O3 Photocatalytic degradation Toluene Spindle-shaped microstructure of alpha-Fe2O3 was successfully synthesized by a simple hydrothermal method. The alpha-Fe2O3/graphene oxide (GO) composites was prepared using a modified Hummers’ strategy. The properties of the samples were systematically investigated by X-ray powder diffraction (XRD), UV–Vis diffuse reflectance spectrophotometer, transmission electron microscope, atomic force microscope, X-ray photoelectron spectroscopy, and Raman spectroscopy (Raman) techniques. GO nanosheets act as supporting materials for anchoring the alpha-Fe2O3 particles. The average crystallite sizes of the alpha-Fe2O3 and alpha-Fe2O3/GO samples are ca. 27 and 24 nm, respectively. The possible growth of alpha-Fe2O3onto GO layers led to a higher absorbance capacity for visible light by a-Fe2O3/GO than alpha-Fe2O3 composite. The photocatalytic degradation of toluene over the alpha-Fe2O3 and alpha-Fe2O3/GO samples under xenon-lamp irradiation was comparatively studied by in situ FTIR technique. The results indicate that the alpha-Fe2O3/GO sample synthesized exhibited a higher capacity for the degradation of toluene. The composite of alpha-Fe2O3/GO could be promisingly applied in photo-driven air purification. 2013 Journal Article http://hdl.handle.net/20.500.11937/27315 10.1007/s11051-013-1670-x Springer Netherlands restricted
spellingShingle In situ FTIR
Graphene oxide
alpha-Fe2O3
Photocatalytic degradation
Toluene
Li, H.
Zhao, Q.
Li, X.
Zhu, Z.
Tade, Moses
Liu, Shaomin
Fabrication, characterization, and photocatalytic property of alpha-Fe2O3/graphene oxide composite
title Fabrication, characterization, and photocatalytic property of alpha-Fe2O3/graphene oxide composite
title_full Fabrication, characterization, and photocatalytic property of alpha-Fe2O3/graphene oxide composite
title_fullStr Fabrication, characterization, and photocatalytic property of alpha-Fe2O3/graphene oxide composite
title_full_unstemmed Fabrication, characterization, and photocatalytic property of alpha-Fe2O3/graphene oxide composite
title_short Fabrication, characterization, and photocatalytic property of alpha-Fe2O3/graphene oxide composite
title_sort fabrication, characterization, and photocatalytic property of alpha-fe2o3/graphene oxide composite
topic In situ FTIR
Graphene oxide
alpha-Fe2O3
Photocatalytic degradation
Toluene
url http://hdl.handle.net/20.500.11937/27315