Enhanced chromium tolerance of La0.6Sr0.4Co0.2Fe0.8O3 − δ electrode of solid oxide fuel cells by Gd0.1Ce0.9O1.95 impregnation

The electrochemical activities and chromium tolerances are studied on single phase La0.6Sr0.4Co0.2Fe0.8O3 − δ (LSCF) and Gd0.1Ce0.9O1.95 (GDC) impregnated LSCF (GDC-LSCF) cathodes of solid oxide fuel cells (SOFCs). GDC-LSCF electrode shows a significantly reduced electrode polarization resistance an...

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Main Authors: Zhao, L., Amarasinghe, S., Jiang, San Ping
Format: Journal Article
Published: 2013
Online Access:http://hdl.handle.net/20.500.11937/26729
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author Zhao, L.
Amarasinghe, S.
Jiang, San Ping
author_facet Zhao, L.
Amarasinghe, S.
Jiang, San Ping
author_sort Zhao, L.
building Curtin Institutional Repository
collection Online Access
description The electrochemical activities and chromium tolerances are studied on single phase La0.6Sr0.4Co0.2Fe0.8O3 − δ (LSCF) and Gd0.1Ce0.9O1.95 (GDC) impregnated LSCF (GDC-LSCF) cathodes of solid oxide fuel cells (SOFCs). GDC-LSCF electrode shows a significantly reduced electrode polarization resistance and more stable performance for the O2 reduction reaction in the presence of chromia-forming metallic interconnect as compared to that on LSCF. The results indicate that the impregnated GDC nanoparticles serve as a barrier layer to enhance the resistance and tolerance of LSCF towards chromium deposition and poisoning.
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institution Curtin University Malaysia
institution_category Local University
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publishDate 2013
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spelling curtin-20.500.11937-267292017-09-13T15:29:59Z Enhanced chromium tolerance of La0.6Sr0.4Co0.2Fe0.8O3 − δ electrode of solid oxide fuel cells by Gd0.1Ce0.9O1.95 impregnation Zhao, L. Amarasinghe, S. Jiang, San Ping The electrochemical activities and chromium tolerances are studied on single phase La0.6Sr0.4Co0.2Fe0.8O3 − δ (LSCF) and Gd0.1Ce0.9O1.95 (GDC) impregnated LSCF (GDC-LSCF) cathodes of solid oxide fuel cells (SOFCs). GDC-LSCF electrode shows a significantly reduced electrode polarization resistance and more stable performance for the O2 reduction reaction in the presence of chromia-forming metallic interconnect as compared to that on LSCF. The results indicate that the impregnated GDC nanoparticles serve as a barrier layer to enhance the resistance and tolerance of LSCF towards chromium deposition and poisoning. 2013 Journal Article http://hdl.handle.net/20.500.11937/26729 10.1016/j.elecom.2013.10.019 restricted
spellingShingle Zhao, L.
Amarasinghe, S.
Jiang, San Ping
Enhanced chromium tolerance of La0.6Sr0.4Co0.2Fe0.8O3 − δ electrode of solid oxide fuel cells by Gd0.1Ce0.9O1.95 impregnation
title Enhanced chromium tolerance of La0.6Sr0.4Co0.2Fe0.8O3 − δ electrode of solid oxide fuel cells by Gd0.1Ce0.9O1.95 impregnation
title_full Enhanced chromium tolerance of La0.6Sr0.4Co0.2Fe0.8O3 − δ electrode of solid oxide fuel cells by Gd0.1Ce0.9O1.95 impregnation
title_fullStr Enhanced chromium tolerance of La0.6Sr0.4Co0.2Fe0.8O3 − δ electrode of solid oxide fuel cells by Gd0.1Ce0.9O1.95 impregnation
title_full_unstemmed Enhanced chromium tolerance of La0.6Sr0.4Co0.2Fe0.8O3 − δ electrode of solid oxide fuel cells by Gd0.1Ce0.9O1.95 impregnation
title_short Enhanced chromium tolerance of La0.6Sr0.4Co0.2Fe0.8O3 − δ electrode of solid oxide fuel cells by Gd0.1Ce0.9O1.95 impregnation
title_sort enhanced chromium tolerance of la0.6sr0.4co0.2fe0.8o3 − δ electrode of solid oxide fuel cells by gd0.1ce0.9o1.95 impregnation
url http://hdl.handle.net/20.500.11937/26729