Sulfur rich petroleum derived from lacustrine carbonate source rocks in Bohai Bay Basin, East China

Crude oils produced from the Zhanhua depression, Bohai Bay Basin are high in sulfur and differ from most lacustrine oils in this basin and elsewhere. Physical properties, biomarker ratios and aromatic hydrocarbon assemblages reveal that they are derived from carbonate source rock horizons. Represent...

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Main Authors: Wang, Guangli, Wang, T., Simoneit, B., Zhang, L., Zhang, X.
Format: Journal Article
Published: Pergamon 2010
Online Access:http://hdl.handle.net/20.500.11937/26454
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author Wang, Guangli
Wang, T.
Simoneit, B.
Zhang, L.
Zhang, X.
author_facet Wang, Guangli
Wang, T.
Simoneit, B.
Zhang, L.
Zhang, X.
author_sort Wang, Guangli
building Curtin Institutional Repository
collection Online Access
description Crude oils produced from the Zhanhua depression, Bohai Bay Basin are high in sulfur and differ from most lacustrine oils in this basin and elsewhere. Physical properties, biomarker ratios and aromatic hydrocarbon assemblages reveal that they are derived from carbonate source rock horizons. Representative source rock samples with abundant organic matter (TOC >∕ 1% and S2 >∕ 5 mg HC/g rock) were selected for further correlation, and their high bitumen contents indicated their indigenousness to saline or carbonate depositional environments. The results of oil–source rock correlation suggest that these sulfur rich heavy oils originate from Es3–4 carbonates and marls limited to the Bonan sag. Maturity assessments with burial history showed that they were expelled at the early oil generation window. High levels of 20S-5α,14α,17α- and 5α,14β,17β-steranes, together with low values for the Ts/(Ts + Tm) ratio and two methylated aromatic ratios, MDR′ and MPI 1, were observed in these oils. Sulfur, associated with evaporite and carbonate environments, is a significant factor not only in controlling the occurrence of biomarker isomers but also for petroleum formation at abnormally low thermal stress levels.
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spelling curtin-20.500.11937-264542017-09-13T15:26:49Z Sulfur rich petroleum derived from lacustrine carbonate source rocks in Bohai Bay Basin, East China Wang, Guangli Wang, T. Simoneit, B. Zhang, L. Zhang, X. Crude oils produced from the Zhanhua depression, Bohai Bay Basin are high in sulfur and differ from most lacustrine oils in this basin and elsewhere. Physical properties, biomarker ratios and aromatic hydrocarbon assemblages reveal that they are derived from carbonate source rock horizons. Representative source rock samples with abundant organic matter (TOC >∕ 1% and S2 >∕ 5 mg HC/g rock) were selected for further correlation, and their high bitumen contents indicated their indigenousness to saline or carbonate depositional environments. The results of oil–source rock correlation suggest that these sulfur rich heavy oils originate from Es3–4 carbonates and marls limited to the Bonan sag. Maturity assessments with burial history showed that they were expelled at the early oil generation window. High levels of 20S-5α,14α,17α- and 5α,14β,17β-steranes, together with low values for the Ts/(Ts + Tm) ratio and two methylated aromatic ratios, MDR′ and MPI 1, were observed in these oils. Sulfur, associated with evaporite and carbonate environments, is a significant factor not only in controlling the occurrence of biomarker isomers but also for petroleum formation at abnormally low thermal stress levels. 2010 Journal Article http://hdl.handle.net/20.500.11937/26454 10.1016/j.orggeochem.2009.12.010 Pergamon restricted
spellingShingle Wang, Guangli
Wang, T.
Simoneit, B.
Zhang, L.
Zhang, X.
Sulfur rich petroleum derived from lacustrine carbonate source rocks in Bohai Bay Basin, East China
title Sulfur rich petroleum derived from lacustrine carbonate source rocks in Bohai Bay Basin, East China
title_full Sulfur rich petroleum derived from lacustrine carbonate source rocks in Bohai Bay Basin, East China
title_fullStr Sulfur rich petroleum derived from lacustrine carbonate source rocks in Bohai Bay Basin, East China
title_full_unstemmed Sulfur rich petroleum derived from lacustrine carbonate source rocks in Bohai Bay Basin, East China
title_short Sulfur rich petroleum derived from lacustrine carbonate source rocks in Bohai Bay Basin, East China
title_sort sulfur rich petroleum derived from lacustrine carbonate source rocks in bohai bay basin, east china
url http://hdl.handle.net/20.500.11937/26454