Adsorption and heterogeneous advanced oxidation of phenolic contaminants using Fe loaded mesoporous SBA-15 and H2O2

Mesoporous silica, SBA-15, supported Fe/SBA-15 catalysts were prepared by impregnation and tested for adsorption and heterogeneous advanced oxidation of 2,4-dichlorophenol (DCP) in aqueous solution using H2O2. Characterisation indicated that Fe impregnation did not change the porous structure of SBA...

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Main Authors: Shukla, Pradeep, Wang, Shaobin, Sun, Hongqi, Ang, Ming, Tade, Moses
Format: Journal Article
Published: Elsevier BV 2010
Online Access:http://hdl.handle.net/20.500.11937/25891
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author Shukla, Pradeep
Wang, Shaobin
Sun, Hongqi
Ang, Ming
Tade, Moses
author_facet Shukla, Pradeep
Wang, Shaobin
Sun, Hongqi
Ang, Ming
Tade, Moses
author_sort Shukla, Pradeep
building Curtin Institutional Repository
collection Online Access
description Mesoporous silica, SBA-15, supported Fe/SBA-15 catalysts were prepared by impregnation and tested for adsorption and heterogeneous advanced oxidation of 2,4-dichlorophenol (DCP) in aqueous solution using H2O2. Characterisation indicated that Fe impregnation did not change the porous structure of SBA-15. Fe/SBA-15 exhibits moderate DCP adsorption, however, Fe/SBA-15 is effective for DCP oxidation under H2O2. The catalytic activity depends on Fe loading, H2O2 concentration, DCP concentration and solution pH. Fe/SBA-15 can achieve 100% DCP conversion and 60% TOC removal at the conditions of 100 ppm DCP, 0.05 g 10%wt Fe/SBA-15, and 1000 ppm H2O2. This catalyst also shows stable performance with low Fe leaching.
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institution Curtin University Malaysia
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last_indexed 2025-11-14T07:58:59Z
publishDate 2010
publisher Elsevier BV
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spelling curtin-20.500.11937-258912017-09-13T15:24:46Z Adsorption and heterogeneous advanced oxidation of phenolic contaminants using Fe loaded mesoporous SBA-15 and H2O2 Shukla, Pradeep Wang, Shaobin Sun, Hongqi Ang, Ming Tade, Moses Mesoporous silica, SBA-15, supported Fe/SBA-15 catalysts were prepared by impregnation and tested for adsorption and heterogeneous advanced oxidation of 2,4-dichlorophenol (DCP) in aqueous solution using H2O2. Characterisation indicated that Fe impregnation did not change the porous structure of SBA-15. Fe/SBA-15 exhibits moderate DCP adsorption, however, Fe/SBA-15 is effective for DCP oxidation under H2O2. The catalytic activity depends on Fe loading, H2O2 concentration, DCP concentration and solution pH. Fe/SBA-15 can achieve 100% DCP conversion and 60% TOC removal at the conditions of 100 ppm DCP, 0.05 g 10%wt Fe/SBA-15, and 1000 ppm H2O2. This catalyst also shows stable performance with low Fe leaching. 2010 Journal Article http://hdl.handle.net/20.500.11937/25891 10.1016/j.cej.2010.08.061 Elsevier BV restricted
spellingShingle Shukla, Pradeep
Wang, Shaobin
Sun, Hongqi
Ang, Ming
Tade, Moses
Adsorption and heterogeneous advanced oxidation of phenolic contaminants using Fe loaded mesoporous SBA-15 and H2O2
title Adsorption and heterogeneous advanced oxidation of phenolic contaminants using Fe loaded mesoporous SBA-15 and H2O2
title_full Adsorption and heterogeneous advanced oxidation of phenolic contaminants using Fe loaded mesoporous SBA-15 and H2O2
title_fullStr Adsorption and heterogeneous advanced oxidation of phenolic contaminants using Fe loaded mesoporous SBA-15 and H2O2
title_full_unstemmed Adsorption and heterogeneous advanced oxidation of phenolic contaminants using Fe loaded mesoporous SBA-15 and H2O2
title_short Adsorption and heterogeneous advanced oxidation of phenolic contaminants using Fe loaded mesoporous SBA-15 and H2O2
title_sort adsorption and heterogeneous advanced oxidation of phenolic contaminants using fe loaded mesoporous sba-15 and h2o2
url http://hdl.handle.net/20.500.11937/25891