Characterization of thermal stability, microstructures and properties of Al2TiO5 - and Ti3SiC2- based ceramics

The focus of this thesis was to study the thermal stability of Al2TiO5- and Ti3SiC2-based ceramics, and the oxidation characteristics of Ti3SiC2 through in-situ x-ray and neutron diffraction. The decomposition behaviour of Al2TiO5 in controlled atmospheres was studied in the temperature range of 20–...

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Main Author: Oo, Zeya
Format: Thesis
Language:English
Published: Curtin University 2013
Online Access:http://hdl.handle.net/20.500.11937/2514
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author Oo, Zeya
author_facet Oo, Zeya
author_sort Oo, Zeya
building Curtin Institutional Repository
collection Online Access
description The focus of this thesis was to study the thermal stability of Al2TiO5- and Ti3SiC2-based ceramics, and the oxidation characteristics of Ti3SiC2 through in-situ x-ray and neutron diffraction. The decomposition behaviour of Al2TiO5 in controlled atmospheres was studied in the temperature range of 20–1400°C. Al2TiO5 decomposed at 1100°C but reformed at 1350°C. In vacuum or argon, Ti3SiC2 decomposed to TiCx and Ti5Si3Cx above 1200°C. In air, Ti3SiC2 oxidized to anatase at 600°C, and formed an outer layer of rutile at 750°C and an inner mixed layer of rutile and cristobalite at 1350°C. Tridymite formed during cooling from 1350°C to room temperature.
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spelling curtin-20.500.11937-25142017-02-20T06:37:30Z Characterization of thermal stability, microstructures and properties of Al2TiO5 - and Ti3SiC2- based ceramics Oo, Zeya The focus of this thesis was to study the thermal stability of Al2TiO5- and Ti3SiC2-based ceramics, and the oxidation characteristics of Ti3SiC2 through in-situ x-ray and neutron diffraction. The decomposition behaviour of Al2TiO5 in controlled atmospheres was studied in the temperature range of 20–1400°C. Al2TiO5 decomposed at 1100°C but reformed at 1350°C. In vacuum or argon, Ti3SiC2 decomposed to TiCx and Ti5Si3Cx above 1200°C. In air, Ti3SiC2 oxidized to anatase at 600°C, and formed an outer layer of rutile at 750°C and an inner mixed layer of rutile and cristobalite at 1350°C. Tridymite formed during cooling from 1350°C to room temperature. 2013 Thesis http://hdl.handle.net/20.500.11937/2514 en Curtin University fulltext
spellingShingle Oo, Zeya
Characterization of thermal stability, microstructures and properties of Al2TiO5 - and Ti3SiC2- based ceramics
title Characterization of thermal stability, microstructures and properties of Al2TiO5 - and Ti3SiC2- based ceramics
title_full Characterization of thermal stability, microstructures and properties of Al2TiO5 - and Ti3SiC2- based ceramics
title_fullStr Characterization of thermal stability, microstructures and properties of Al2TiO5 - and Ti3SiC2- based ceramics
title_full_unstemmed Characterization of thermal stability, microstructures and properties of Al2TiO5 - and Ti3SiC2- based ceramics
title_short Characterization of thermal stability, microstructures and properties of Al2TiO5 - and Ti3SiC2- based ceramics
title_sort characterization of thermal stability, microstructures and properties of al2tio5 - and ti3sic2- based ceramics
url http://hdl.handle.net/20.500.11937/2514