Visible light photocatalytic degradation of organics on nanoparticles of bi-metallic oxides

Various bi-metallic oxides, Bi2WO6, AgVO3, AgTaO3, BiTaO4, Cd2Ta2O7, InTaO4, CoTa2O6, CeTaO4 and EuTaO4, were synthesized by a solution method and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), UV–vis diffuse reflectance spectroscopy, and Fourier transform infrared spe...

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Main Authors: Ullah, R, Sun, Hongqi, Ang, Ming, Tade, Moses, Wang, Shaobin
Format: Journal Article
Published: Pergamon 2012
Subjects:
Online Access:http://hdl.handle.net/20.500.11937/25131
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author Ullah, R
Sun, Hongqi
Ang, Ming
Tade, Moses
Wang, Shaobin
author_facet Ullah, R
Sun, Hongqi
Ang, Ming
Tade, Moses
Wang, Shaobin
author_sort Ullah, R
building Curtin Institutional Repository
collection Online Access
description Various bi-metallic oxides, Bi2WO6, AgVO3, AgTaO3, BiTaO4, Cd2Ta2O7, InTaO4, CoTa2O6, CeTaO4 and EuTaO4, were synthesized by a solution method and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), UV–vis diffuse reflectance spectroscopy, and Fourier transform infrared spectroscopy (FTIR). All the materials were tested for photocatalytic decomposition of VOCs such as aqueous methylene blue and gaseous toluene. Results indicated that tantalum based ternary compounds like Cd2Ta2O7, AgTaO3 and BiTaO4 could decompose gaseous toluene under visible light irradiation at a much faster rate than TiO2. These compounds also demonstrated very stable activity under UV light irradiation in a longer period of time. Tantalum based compounds could also decompose methylene blue under UV–vis light irradiation but they exhibited lower activity than Bi2WO6 and AgVO3.
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institution Curtin University Malaysia
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publishDate 2012
publisher Pergamon
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spelling curtin-20.500.11937-251312017-09-13T15:21:51Z Visible light photocatalytic degradation of organics on nanoparticles of bi-metallic oxides Ullah, R Sun, Hongqi Ang, Ming Tade, Moses Wang, Shaobin Visiblelight Toluene Methylene blue Photocatalysis Ta-based oxide Various bi-metallic oxides, Bi2WO6, AgVO3, AgTaO3, BiTaO4, Cd2Ta2O7, InTaO4, CoTa2O6, CeTaO4 and EuTaO4, were synthesized by a solution method and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), UV–vis diffuse reflectance spectroscopy, and Fourier transform infrared spectroscopy (FTIR). All the materials were tested for photocatalytic decomposition of VOCs such as aqueous methylene blue and gaseous toluene. Results indicated that tantalum based ternary compounds like Cd2Ta2O7, AgTaO3 and BiTaO4 could decompose gaseous toluene under visible light irradiation at a much faster rate than TiO2. These compounds also demonstrated very stable activity under UV light irradiation in a longer period of time. Tantalum based compounds could also decompose methylene blue under UV–vis light irradiation but they exhibited lower activity than Bi2WO6 and AgVO3. 2012 Journal Article http://hdl.handle.net/20.500.11937/25131 10.1016/j.seppur.2012.01.014 Pergamon restricted
spellingShingle Visiblelight
Toluene
Methylene blue
Photocatalysis
Ta-based oxide
Ullah, R
Sun, Hongqi
Ang, Ming
Tade, Moses
Wang, Shaobin
Visible light photocatalytic degradation of organics on nanoparticles of bi-metallic oxides
title Visible light photocatalytic degradation of organics on nanoparticles of bi-metallic oxides
title_full Visible light photocatalytic degradation of organics on nanoparticles of bi-metallic oxides
title_fullStr Visible light photocatalytic degradation of organics on nanoparticles of bi-metallic oxides
title_full_unstemmed Visible light photocatalytic degradation of organics on nanoparticles of bi-metallic oxides
title_short Visible light photocatalytic degradation of organics on nanoparticles of bi-metallic oxides
title_sort visible light photocatalytic degradation of organics on nanoparticles of bi-metallic oxides
topic Visiblelight
Toluene
Methylene blue
Photocatalysis
Ta-based oxide
url http://hdl.handle.net/20.500.11937/25131