Combining thio-bromo Click chemistry and raft polymerization: a powerful tool for preparing functionalized multiblock and hyperbranched polymers

QR Code

Combining thio-bromo Click chemistry and raft polymerization: a powerful tool for preparing functionalized multiblock and hyperbranched polymers

An experiment was conducted to prove that RAFT-prepared polymers can serve as convenient masked macromolecular thiols suitable for thio-bromo reactions. Homopolymers were prepared by RAFT polymerization using 4-cyanopentanoic acid dithiobenzoate (CPADB) as the chain transfer agent, yielding homopoly...

Full description

Bibliographic Details
Main Authors:	Xu, J., Tao, L., Boyer, C., Lowe, Andrew, Davis, T.
Format:	Journal Article
Published:	American Chemical Society 2010
Online Access:	http://hdl.handle.net/20.500.11937/25045

Similar Items

Combining RAFT radical polymerization and click/highly efficient coupling chemistries: A powerful strategy for the preparation of novel materials
by: Harvison, M., et al.
Published: (2011)

RAFT polymerization and thiol chemistry: A complementary pairing for implementing modern macromolecular design
by: Roth, P., et al.
Published: (2011)

RAFT Polymerization in Homogeneous Aqueous Media: Initiation Systems, RAFT Agent Stability, Monomers and Polymer Structures
by: Lowe, Andrew, et al.
Published: (2008)

Thiol-based click chemistries in polymer: Synthesis and modification
by: Lowe, Andrew, et al.
Published: (2010)

RAFT alcoholic dispersion polymerization with polymerization-induced self-assembly
by: Lowe, Andrew
Published: (2016)

Novel α,α-Bischolesteryl Functional (Co)Polymers: RAFT Radical Polymerization Synthesis and Preliminary Solution Characterization
by: Roth, Peter, et al.
Published: (2014)

End-Group Functionalization of RAFT-prepared Polymers Using Thiol-X Chemistries
by: Lowe, Andrew
Published: (2013)

Nucleophilic thiol-Michael chemistry and hyperbranched (co)polymers: Synthesis and ring-opening metathesis (co)polymerization of novel difunctional exo-7-oxanorbornenes with in situ inimer formation
by: Liu, M., et al.
Published: (2013)

Functional (Co)Polymers via a Combination of Reversible Deactivation Radical Polymerisation Techniques and Thiol-based ‘Click’/Conjugation Chemistries
by: Lowe, Andrew
Published: (2017)

The thiol-isocyanate click reaction: Facile and quantitative access to ?-end-functional poly(N,N-diethylacrylamide) synthesized by RAFT radical polymerization
by: Li, H., et al.
Published: (2009)

Facile Access to Polymeric Vesicular Nanostructures: Remarkable ω-End group Effects in Cholesterol and Pyrene Functional (Co)Polymers
by: Xu, J., et al.
Published: (2011)

Thiol-yne ‘click’/coupling chemistry and recent applications in polymer and materials synthesis and modification
by: Lowe, Andrew
Published: (2014)

Thiol-click chemistry: A multifaceted toolbox for small molecule and polymer synthesis
by: Hoyle, C., et al.
Published: (2010)

Polymerization-Induced Self-Assembly: Ethanolic RAFT Dispersion Polymerization of 2 Phenylethyl Methacrylate
by: Pei, Y., et al.
Published: (2014)

End group reactions of RAFT-Prepared (Co)polymers
by: Harvison, M., et al.
Published: (2011)

Synthesis and application of novel hyperbranched polymers
by: Goodwin, Sophie, R
Published: (2021)

The nucleophilic, phosphine-catalyzed thiol-ene click reaction and convergent star synthesis with RAFT-prepared homopolymers
by: Chan, J., et al.
Published: (2009)

Convergent synthesis of 3-arm star polymers from RAFT-prepared poly(N,N-diethylacrylamide) via a thiol-ene click reaction
by: Chan, J., et al.
Published: (2008)

Preparation of hyperbranched polymers by controlled/living polymerisations
by: Zheng, Yu
Published: (2010)

Click chemistry in carbon nanoreactors
by: Rance, Graham A., et al.
Published: (2013)

Hyperbranched polymers as non-viral vectors for gene delivery
by: Alazzo, Ali
Published: (2018)

Modification of NanoCrystalline Cellulose (NCC) by Hyperbranched Polymer
by: Zianor Azrina, Z. A., et al.
Published: (2017)

Synthesis of Di- and tri-tertiary amine containing methacrylic monomers and their (Co)polymerization via RAFT
by: Yu, B., et al.
Published: (2009)

Thiol-yne click chemistry: A powerful and versatile methodology for materials synthesis
by: Lowe, Andrew, et al.
Published: (2010)

Thiol-ene "click" reactions and recent applications in polymer and materials synthesis
by: Lowe, Andrew
Published: (2010)

Synthesis and characterisation of non-ionic AB-diblock nanoparticles prepared by RAFT dispersion polymerization with polymerization-induced self-assembly
by: Pei, Y., et al.
Published: (2016)

Microwave-assisted synthesis of block copolymer nanoparticles via RAFT with polymerization-induced self-assembly in methanol
by: Garrett, E., et al.
Published: (2016)

Thiol-reactive Passerini-methacrylates and Polymorphic Surface Functional Soft Matter Nanoparticles via Ethanolic RAFT Dispersion Polymerization and Post-polymerization Modification
by: Pei, Y., et al.
Published: (2015)

Soft Matter Nanoparticles with Reactive Coronal Pentafluorophenyl Methacrylate Residues via Non-Polar RAFT Dispersion Polymerization and Polymerization-Induced Self-Assembly
by: Pei, Y., et al.
Published: (2015)

Multiblock Backward Differentiation Formulae for solving first order ordinary differential equations
by: Mohd Nasir, Nor Ain Azeany
Published: (2011)

RAFT Dispersion Polymerization in Nonpolar Media: Polymerization of 3-Phenylpropyl Methacrylate in n-Tetradecane with Poly(stearyl methacrylate) Homopolymers as Macro Chain Transfer Agents
by: Pei, Y., et al.
Published: (2015)

Macromolecular thiolysis of oxiranes: End-group modification of RAFT prepared homopolymers
by: Harvison, M., et al.
Published: (2011)

Thiol-ene “Click” Reactions and Recent Applications in Polymer and Materials Synthesis: A First Update
by: Lowe, Andrew
Published: (2014)

Monovalent Maleimide Functionalization of Gold Nanoparticles Via Copper-Free Click Chemistry
by: D. J., Nieves, et al.
Published: (2014)

Click Chemistry: developing new tools & reactions for practical applications
by: Barrow, Andrew S.
Published: (2017)

Apostasy and religious freedom: a response to Thio Li-ann
by: Ab Aziz, Shamrahayu
Published: (2007)

Molecularly imprinted polymer synthesis using RAFT polymerisation
by: Cormack, Peter A.G., et al.
Published: (2013)

Versatile "click chemistry" Approach to functionalizing silicon quantum dots: Applications toward fluorescent cellular imaging
by: Cheng, X., et al.
Published: (2014)

Click chemistry in mesoporous materials: Functionalization of porous silicon rugate filters
by: Ciampi, Simone, et al.
Published: (2008)

ROMP (co)polymers with pendent alkyne side groups: post-polymerization modification employing thiol–yne and CuAAC coupling chemistries
by: van Hensbergen, J., et al.
Published: (2014)

Cannot write session to /tmp/vufind_sessions/sess_b12t6b99d58j6bmu9e8la72gbi