Silver(I), gold(I) and palladium(II) complexes of a NHC-pincer ligand with an aminotriazine core: a comparison with pyridyl analogues
Dinuclear silver, di- and tetra-nuclear gold, and mononuclear palladium complexes with chelating C,N,C diethylaminotriazinyl-bridged bis(NHC) pincer ligands were prepared and characterised. The silver and gold complexes exist in a twisted, helical conformation in both the solution- and the solid sta...
| Main Authors: | , , , , , , |
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| Format: | Journal Article |
| Published: |
2015
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| Online Access: | http://hdl.handle.net/20.500.11937/23959 |
| _version_ | 1848751297428193280 |
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| author | Vaughan, Jeffrey Carter, Damien Rohl, Andrew Ogden, Mark Skelton, B. Simpson, Peter Brown, David |
| author_facet | Vaughan, Jeffrey Carter, Damien Rohl, Andrew Ogden, Mark Skelton, B. Simpson, Peter Brown, David |
| author_sort | Vaughan, Jeffrey |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | Dinuclear silver, di- and tetra-nuclear gold, and mononuclear palladium complexes with chelating C,N,C diethylaminotriazinyl-bridged bis(NHC) pincer ligands were prepared and characterised. The silver and gold complexes exist in a twisted, helical conformation in both the solution- and the solid state. In contrast, an analogous dinuclear gold complex with pyridyl-bridged NHCs exists in a linear conformation. Computational studies have been performed to rationalise the formation of twisted/helical vs. linear forms. |
| first_indexed | 2025-11-14T07:50:29Z |
| format | Journal Article |
| id | curtin-20.500.11937-23959 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T07:50:29Z |
| publishDate | 2015 |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-239592017-09-13T15:47:18Z Silver(I), gold(I) and palladium(II) complexes of a NHC-pincer ligand with an aminotriazine core: a comparison with pyridyl analogues Vaughan, Jeffrey Carter, Damien Rohl, Andrew Ogden, Mark Skelton, B. Simpson, Peter Brown, David Dinuclear silver, di- and tetra-nuclear gold, and mononuclear palladium complexes with chelating C,N,C diethylaminotriazinyl-bridged bis(NHC) pincer ligands were prepared and characterised. The silver and gold complexes exist in a twisted, helical conformation in both the solution- and the solid state. In contrast, an analogous dinuclear gold complex with pyridyl-bridged NHCs exists in a linear conformation. Computational studies have been performed to rationalise the formation of twisted/helical vs. linear forms. 2015 Journal Article http://hdl.handle.net/20.500.11937/23959 10.1039/c5dt04213e fulltext |
| spellingShingle | Vaughan, Jeffrey Carter, Damien Rohl, Andrew Ogden, Mark Skelton, B. Simpson, Peter Brown, David Silver(I), gold(I) and palladium(II) complexes of a NHC-pincer ligand with an aminotriazine core: a comparison with pyridyl analogues |
| title | Silver(I), gold(I) and palladium(II) complexes of a NHC-pincer ligand with an aminotriazine core: a comparison with pyridyl analogues |
| title_full | Silver(I), gold(I) and palladium(II) complexes of a NHC-pincer ligand with an aminotriazine core: a comparison with pyridyl analogues |
| title_fullStr | Silver(I), gold(I) and palladium(II) complexes of a NHC-pincer ligand with an aminotriazine core: a comparison with pyridyl analogues |
| title_full_unstemmed | Silver(I), gold(I) and palladium(II) complexes of a NHC-pincer ligand with an aminotriazine core: a comparison with pyridyl analogues |
| title_short | Silver(I), gold(I) and palladium(II) complexes of a NHC-pincer ligand with an aminotriazine core: a comparison with pyridyl analogues |
| title_sort | silver(i), gold(i) and palladium(ii) complexes of a nhc-pincer ligand with an aminotriazine core: a comparison with pyridyl analogues |
| url | http://hdl.handle.net/20.500.11937/23959 |