Top-of-the-Line Corrosion in The Presence of Hydrocarbon Co-Condensation in Flowing Condition

During the transportation of wet gas, temperature gradient between the internals of the pipeline and the outside environment leads to the condensation of water vapor. Freshly condensed water is very corrosive and can lead to the so-called Top-of-the-Line Corrosion (TLC). However, a certain fraction...

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Main Authors: Pojtanabuntoeng, Thunyaluk, Singer, M., Nesic, S.
Other Authors: Lorrie Krebs (Chair)
Format: Conference Paper
Published: Curran Associates 2012
Subjects:
Online Access:http://www.icmt.ohio.edu/documents/NACE2012/C2012-0001534.pdf
http://hdl.handle.net/20.500.11937/23867
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author Pojtanabuntoeng, Thunyaluk
Singer, M.
Nesic, S.
author2 Lorrie Krebs (Chair)
author_facet Lorrie Krebs (Chair)
Pojtanabuntoeng, Thunyaluk
Singer, M.
Nesic, S.
author_sort Pojtanabuntoeng, Thunyaluk
building Curtin Institutional Repository
collection Online Access
description During the transportation of wet gas, temperature gradient between the internals of the pipeline and the outside environment leads to the condensation of water vapor. Freshly condensed water is very corrosive and can lead to the so-called Top-of-the-Line Corrosion (TLC). However, a certain fraction of hydrocarbons will co-condense along with the water vapor resulting in two immiscible liquids at the pipe wall with a different wettability and different corrosivity. To elucidate the role of co-condensation, corrosion tests in the absence and presence of hydrocarbon were conducted. In the experiments, hot vapors of water and n-heptane saturated with CO2 were generated and transported through a one-inch internal diameter condenser tube, with 2 carbon steel samples located at the inlet and outlet of the tube. Condensation took place on the inner surface of the tube and was related to the TLC. Corrosion rate was evaluated by the weight loss method. In the absence of co-condensation, corrosion rates increased with water condensation rates. In the presence of n-heptane co-condensation, water condensation rates had less influence on the corrosion rates. Iron carbonate (FeCO3) was observed only in the co-condensation scenario, suggesting the change of the chemistry of condensed water
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spelling curtin-20.500.11937-238672017-01-30T12:39:41Z Top-of-the-Line Corrosion in The Presence of Hydrocarbon Co-Condensation in Flowing Condition Pojtanabuntoeng, Thunyaluk Singer, M. Nesic, S. Lorrie Krebs (Chair) co-condensation top of the line corrosion CO2 corrosion During the transportation of wet gas, temperature gradient between the internals of the pipeline and the outside environment leads to the condensation of water vapor. Freshly condensed water is very corrosive and can lead to the so-called Top-of-the-Line Corrosion (TLC). However, a certain fraction of hydrocarbons will co-condense along with the water vapor resulting in two immiscible liquids at the pipe wall with a different wettability and different corrosivity. To elucidate the role of co-condensation, corrosion tests in the absence and presence of hydrocarbon were conducted. In the experiments, hot vapors of water and n-heptane saturated with CO2 were generated and transported through a one-inch internal diameter condenser tube, with 2 carbon steel samples located at the inlet and outlet of the tube. Condensation took place on the inner surface of the tube and was related to the TLC. Corrosion rate was evaluated by the weight loss method. In the absence of co-condensation, corrosion rates increased with water condensation rates. In the presence of n-heptane co-condensation, water condensation rates had less influence on the corrosion rates. Iron carbonate (FeCO3) was observed only in the co-condensation scenario, suggesting the change of the chemistry of condensed water 2012 Conference Paper http://hdl.handle.net/20.500.11937/23867 http://www.icmt.ohio.edu/documents/NACE2012/C2012-0001534.pdf Curran Associates restricted
spellingShingle co-condensation
top of the line corrosion
CO2 corrosion
Pojtanabuntoeng, Thunyaluk
Singer, M.
Nesic, S.
Top-of-the-Line Corrosion in The Presence of Hydrocarbon Co-Condensation in Flowing Condition
title Top-of-the-Line Corrosion in The Presence of Hydrocarbon Co-Condensation in Flowing Condition
title_full Top-of-the-Line Corrosion in The Presence of Hydrocarbon Co-Condensation in Flowing Condition
title_fullStr Top-of-the-Line Corrosion in The Presence of Hydrocarbon Co-Condensation in Flowing Condition
title_full_unstemmed Top-of-the-Line Corrosion in The Presence of Hydrocarbon Co-Condensation in Flowing Condition
title_short Top-of-the-Line Corrosion in The Presence of Hydrocarbon Co-Condensation in Flowing Condition
title_sort top-of-the-line corrosion in the presence of hydrocarbon co-condensation in flowing condition
topic co-condensation
top of the line corrosion
CO2 corrosion
url http://www.icmt.ohio.edu/documents/NACE2012/C2012-0001534.pdf
http://hdl.handle.net/20.500.11937/23867