A combined voltammetric and synchrotron radiation-grazing incidence X-ray diffraction study of the electrocrystallization of zinc tetracyanoquinodimethane
The in situ electrocrystallization of zinc tetracyanoquinodimethane (TCNQ) has been explored using synchrotron radiation-grazing incidence X-ray diffraction (SR-GIXRD) at potentials in the region of the cyclic voltammetric peak where reduction of TCNQ to TCNQ– occurs at a Pt electrode in acetonitril...
| Main Authors: | , , , , |
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| Format: | Journal Article |
| Published: |
2012
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| Online Access: | http://hdl.handle.net/20.500.11937/23641 |
| _version_ | 1848751206933987328 |
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| author | Veder, J. Nafady, A. Clarke, G. De Marco, Roland Bond, A. |
| author_facet | Veder, J. Nafady, A. Clarke, G. De Marco, Roland Bond, A. |
| author_sort | Veder, J. |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | The in situ electrocrystallization of zinc tetracyanoquinodimethane (TCNQ) has been explored using synchrotron radiation-grazing incidence X-ray diffraction (SR-GIXRD) at potentials in the region of the cyclic voltammetric peak where reduction of TCNQ to TCNQ– occurs at a Pt electrode in acetonitrile (0.1 M [NBu4][PF6]) solution containing Zn(NO3)2·6H2O. The in situ SR-GIXRD data along with ex situ IR and Raman spectroscopy results all confirmed the formation of the kinetically favoured phase of Zn[TCNQ]2(H2O)2 as the product. |
| first_indexed | 2025-11-14T07:49:03Z |
| format | Journal Article |
| id | curtin-20.500.11937-23641 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T07:49:03Z |
| publishDate | 2012 |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-236412017-09-13T13:59:02Z A combined voltammetric and synchrotron radiation-grazing incidence X-ray diffraction study of the electrocrystallization of zinc tetracyanoquinodimethane Veder, J. Nafady, A. Clarke, G. De Marco, Roland Bond, A. The in situ electrocrystallization of zinc tetracyanoquinodimethane (TCNQ) has been explored using synchrotron radiation-grazing incidence X-ray diffraction (SR-GIXRD) at potentials in the region of the cyclic voltammetric peak where reduction of TCNQ to TCNQ– occurs at a Pt electrode in acetonitrile (0.1 M [NBu4][PF6]) solution containing Zn(NO3)2·6H2O. The in situ SR-GIXRD data along with ex situ IR and Raman spectroscopy results all confirmed the formation of the kinetically favoured phase of Zn[TCNQ]2(H2O)2 as the product. 2012 Journal Article http://hdl.handle.net/20.500.11937/23641 10.1071/CH11361 restricted |
| spellingShingle | Veder, J. Nafady, A. Clarke, G. De Marco, Roland Bond, A. A combined voltammetric and synchrotron radiation-grazing incidence X-ray diffraction study of the electrocrystallization of zinc tetracyanoquinodimethane |
| title | A combined voltammetric and synchrotron radiation-grazing incidence X-ray diffraction study of the electrocrystallization of zinc tetracyanoquinodimethane |
| title_full | A combined voltammetric and synchrotron radiation-grazing incidence X-ray diffraction study of the electrocrystallization of zinc tetracyanoquinodimethane |
| title_fullStr | A combined voltammetric and synchrotron radiation-grazing incidence X-ray diffraction study of the electrocrystallization of zinc tetracyanoquinodimethane |
| title_full_unstemmed | A combined voltammetric and synchrotron radiation-grazing incidence X-ray diffraction study of the electrocrystallization of zinc tetracyanoquinodimethane |
| title_short | A combined voltammetric and synchrotron radiation-grazing incidence X-ray diffraction study of the electrocrystallization of zinc tetracyanoquinodimethane |
| title_sort | combined voltammetric and synchrotron radiation-grazing incidence x-ray diffraction study of the electrocrystallization of zinc tetracyanoquinodimethane |
| url | http://hdl.handle.net/20.500.11937/23641 |