Preliminary studies into the effect of environmental degradation on the characterisation of automotive clear coats by attenuated total reflectance infrared spectroscopy

This paper presents a study into the impact of environmental weathering on the chemometric classification of automotive clear coats. These studies were conducted using attenuated total reflectance infrared spectroscopy, in conjunction with a chemometric model capable of predicting the country of veh...

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Main Authors: Sauzier, Georgina, Maric, Marc, Van Bronswijk, Wilhelm, Lewis, Simon
Format: Journal Article
Published: R S C Publications 2013
Subjects:
Online Access:http://hdl.handle.net/20.500.11937/23620
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author Sauzier, Georgina
Maric, Marc
Van Bronswijk, Wilhelm
Lewis, Simon
author_facet Sauzier, Georgina
Maric, Marc
Van Bronswijk, Wilhelm
Lewis, Simon
author_sort Sauzier, Georgina
building Curtin Institutional Repository
collection Online Access
description This paper presents a study into the impact of environmental weathering on the chemometric classification of automotive clear coats. These studies were conducted using attenuated total reflectance infrared spectroscopy, in conjunction with a chemometric model capable of predicting the country of vehicle manufacture for a sample based upon its infrared spectrum. Testing of three samples exposed to environmental conditions found the model to be robust to weathering over at least an eight-month period. However, analysis of 12 samples of unknown prior history found that extreme degradation over at least a 10-year period, or the presence of a post-manufacture (respray) coating, could result in misclassification when relying solely on analysis of the clear coat. It is therefore important that cross-sections comprising the full layer sequence of the paint system are obtained wherever possible, as analysis of the underlying layers may give more comprehensive characterisation.
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institution Curtin University Malaysia
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publishDate 2013
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spelling curtin-20.500.11937-236202017-09-13T13:59:39Z Preliminary studies into the effect of environmental degradation on the characterisation of automotive clear coats by attenuated total reflectance infrared spectroscopy Sauzier, Georgina Maric, Marc Van Bronswijk, Wilhelm Lewis, Simon infrared spectroscopy automotive clear coats environmental degradation This paper presents a study into the impact of environmental weathering on the chemometric classification of automotive clear coats. These studies were conducted using attenuated total reflectance infrared spectroscopy, in conjunction with a chemometric model capable of predicting the country of vehicle manufacture for a sample based upon its infrared spectrum. Testing of three samples exposed to environmental conditions found the model to be robust to weathering over at least an eight-month period. However, analysis of 12 samples of unknown prior history found that extreme degradation over at least a 10-year period, or the presence of a post-manufacture (respray) coating, could result in misclassification when relying solely on analysis of the clear coat. It is therefore important that cross-sections comprising the full layer sequence of the paint system are obtained wherever possible, as analysis of the underlying layers may give more comprehensive characterisation. 2013 Journal Article http://hdl.handle.net/20.500.11937/23620 10.1039/c3ay40458g R S C Publications fulltext
spellingShingle infrared spectroscopy
automotive clear coats
environmental degradation
Sauzier, Georgina
Maric, Marc
Van Bronswijk, Wilhelm
Lewis, Simon
Preliminary studies into the effect of environmental degradation on the characterisation of automotive clear coats by attenuated total reflectance infrared spectroscopy
title Preliminary studies into the effect of environmental degradation on the characterisation of automotive clear coats by attenuated total reflectance infrared spectroscopy
title_full Preliminary studies into the effect of environmental degradation on the characterisation of automotive clear coats by attenuated total reflectance infrared spectroscopy
title_fullStr Preliminary studies into the effect of environmental degradation on the characterisation of automotive clear coats by attenuated total reflectance infrared spectroscopy
title_full_unstemmed Preliminary studies into the effect of environmental degradation on the characterisation of automotive clear coats by attenuated total reflectance infrared spectroscopy
title_short Preliminary studies into the effect of environmental degradation on the characterisation of automotive clear coats by attenuated total reflectance infrared spectroscopy
title_sort preliminary studies into the effect of environmental degradation on the characterisation of automotive clear coats by attenuated total reflectance infrared spectroscopy
topic infrared spectroscopy
automotive clear coats
environmental degradation
url http://hdl.handle.net/20.500.11937/23620