Rutile compositions in the Kalgoorlie Goldfields and their implications for exploration

The compositions of 188 grains of rutile from 12 samples from the Kalgoorlie Goldfields, in the Yilgarn Craton of Western Australia, show that grains associated with the Mt Charlotte stockwork-style mineralisation have generally low minor-element contents (except for Fe, which may reflect, in part,...

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Main Authors: Scott, K., Radford, N., Hough, R., Reddy, Steven
Format: Journal Article
Published: Taylor & Francis Co Ltd 2011
Subjects:
Online Access:http://hdl.handle.net/20.500.11937/23203
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author Scott, K.
Radford, N.
Hough, R.
Reddy, Steven
author_facet Scott, K.
Radford, N.
Hough, R.
Reddy, Steven
author_sort Scott, K.
building Curtin Institutional Repository
collection Online Access
description The compositions of 188 grains of rutile from 12 samples from the Kalgoorlie Goldfields, in the Yilgarn Craton of Western Australia, show that grains associated with the Mt Charlotte stockwork-style mineralisation have generally low minor-element contents (except for Fe, which may reflect, in part, ilmenite inclusions). However, rutile in the Fimiston (Golden Mile) lode-style mineralisation is (Fe + W)-rich, and in the high-grade Green Leader mineralisation rutile is (V + W)-rich. The incorporation of W6+ into the rutile structure in these styles of mineralisation is balanced by the presence of Fe3+ and V3+, although in rutile in the Green Leader mineralisation, V is present in both +3 and higher oxidation states. Detailed examination of W-rich rutiles from the Fimiston lode indicates that they have a complex internal microstructure, with variations in lattice orientation within single rutile crystals, probably caused by the strain associated with incorporation of large amounts of foreign ions into the rutile structure. The composition and complex microstructure of rutile can potentially discriminate between Au anomalies of higher and lower significance in the region (lode- vs stockwork-style), with the presence of V in high oxidation states suggesting that the hydrothermal fluids responsible were relatively oxidising.
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spelling curtin-20.500.11937-232032017-09-13T16:07:59Z Rutile compositions in the Kalgoorlie Goldfields and their implications for exploration Scott, K. Radford, N. Hough, R. Reddy, Steven W V rutile geochemistry Golden Mile Mount Charlotte Kalgoorlie The compositions of 188 grains of rutile from 12 samples from the Kalgoorlie Goldfields, in the Yilgarn Craton of Western Australia, show that grains associated with the Mt Charlotte stockwork-style mineralisation have generally low minor-element contents (except for Fe, which may reflect, in part, ilmenite inclusions). However, rutile in the Fimiston (Golden Mile) lode-style mineralisation is (Fe + W)-rich, and in the high-grade Green Leader mineralisation rutile is (V + W)-rich. The incorporation of W6+ into the rutile structure in these styles of mineralisation is balanced by the presence of Fe3+ and V3+, although in rutile in the Green Leader mineralisation, V is present in both +3 and higher oxidation states. Detailed examination of W-rich rutiles from the Fimiston lode indicates that they have a complex internal microstructure, with variations in lattice orientation within single rutile crystals, probably caused by the strain associated with incorporation of large amounts of foreign ions into the rutile structure. The composition and complex microstructure of rutile can potentially discriminate between Au anomalies of higher and lower significance in the region (lode- vs stockwork-style), with the presence of V in high oxidation states suggesting that the hydrothermal fluids responsible were relatively oxidising. 2011 Journal Article http://hdl.handle.net/20.500.11937/23203 10.1080/08120099.2011.600334 Taylor & Francis Co Ltd restricted
spellingShingle W
V
rutile geochemistry
Golden Mile
Mount Charlotte
Kalgoorlie
Scott, K.
Radford, N.
Hough, R.
Reddy, Steven
Rutile compositions in the Kalgoorlie Goldfields and their implications for exploration
title Rutile compositions in the Kalgoorlie Goldfields and their implications for exploration
title_full Rutile compositions in the Kalgoorlie Goldfields and their implications for exploration
title_fullStr Rutile compositions in the Kalgoorlie Goldfields and their implications for exploration
title_full_unstemmed Rutile compositions in the Kalgoorlie Goldfields and their implications for exploration
title_short Rutile compositions in the Kalgoorlie Goldfields and their implications for exploration
title_sort rutile compositions in the kalgoorlie goldfields and their implications for exploration
topic W
V
rutile geochemistry
Golden Mile
Mount Charlotte
Kalgoorlie
url http://hdl.handle.net/20.500.11937/23203