Eu2+/Sm3+ ions co-doped white light luminescence SrSiO3 glass-ceramics phosphor for White LED

Eu2+/Sm3+ co-doped silicate glass was prepared by high temperature melting under reducing atmosphere and the Eu 2+/Sm3+ co-doped SrSiO3 transparent glass-ceramics were obtained after heat-treatment. X-ray diffraction (XRD) and Raman spectra confirmed the formation of SrSiO3 nano-crystals in the glas...

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Main Authors: Cui, Z., Ye, R., Deng, D., Hua, Y., Zhao, S., Jia, Guohua, Li, C., Xu, S.
Format: Journal Article
Published: Elsevier B.V. 2011
Online Access:http://hdl.handle.net/20.500.11937/20198
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author Cui, Z.
Ye, R.
Deng, D.
Hua, Y.
Zhao, S.
Jia, Guohua
Li, C.
Xu, S.
author_facet Cui, Z.
Ye, R.
Deng, D.
Hua, Y.
Zhao, S.
Jia, Guohua
Li, C.
Xu, S.
author_sort Cui, Z.
building Curtin Institutional Repository
collection Online Access
description Eu2+/Sm3+ co-doped silicate glass was prepared by high temperature melting under reducing atmosphere and the Eu 2+/Sm3+ co-doped SrSiO3 transparent glass-ceramics were obtained after heat-treatment. X-ray diffraction (XRD) and Raman spectra confirmed the formation of SrSiO3 nano-crystals in the glass matrix. The photoluminescence excitation (PLE) spectra and photoluminescence (PL) spectra of the samples were measured. A broad emission band from 400 nm to 550 nm due to the 4f65d1 ? 4f7 transitions of Eu2+ was observed, as well as several sharp emission peaks at 563 nm, 600 nm, 646 nm and 713 nm ascribed to the 4f ? 4f transitions of Sm3+. The luminescence properties of the glass ceramics with different molar ratio of Eu2+/Sm3+ were studied and the corresponding chromaticity coordinates were calculated. The ultraviolet light-emitting diode (UV-LED) excitable glass-ceramics emitting white light were obtained by tuning the relative emission intensity of Eu 2+ and Sm3+. The results indicate that the Eu 2+/Sm3+ co-doped SrSiO3 transparent glass-ceramics can be used as a potential matrix material for White LED under UV-LED excitation. © 2010 Elsevier B.V. All rights reserved.
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institution Curtin University Malaysia
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publishDate 2011
publisher Elsevier B.V.
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spelling curtin-20.500.11937-201982017-09-13T13:49:38Z Eu2+/Sm3+ ions co-doped white light luminescence SrSiO3 glass-ceramics phosphor for White LED Cui, Z. Ye, R. Deng, D. Hua, Y. Zhao, S. Jia, Guohua Li, C. Xu, S. Eu2+/Sm3+ co-doped silicate glass was prepared by high temperature melting under reducing atmosphere and the Eu 2+/Sm3+ co-doped SrSiO3 transparent glass-ceramics were obtained after heat-treatment. X-ray diffraction (XRD) and Raman spectra confirmed the formation of SrSiO3 nano-crystals in the glass matrix. The photoluminescence excitation (PLE) spectra and photoluminescence (PL) spectra of the samples were measured. A broad emission band from 400 nm to 550 nm due to the 4f65d1 ? 4f7 transitions of Eu2+ was observed, as well as several sharp emission peaks at 563 nm, 600 nm, 646 nm and 713 nm ascribed to the 4f ? 4f transitions of Sm3+. The luminescence properties of the glass ceramics with different molar ratio of Eu2+/Sm3+ were studied and the corresponding chromaticity coordinates were calculated. The ultraviolet light-emitting diode (UV-LED) excitable glass-ceramics emitting white light were obtained by tuning the relative emission intensity of Eu 2+ and Sm3+. The results indicate that the Eu 2+/Sm3+ co-doped SrSiO3 transparent glass-ceramics can be used as a potential matrix material for White LED under UV-LED excitation. © 2010 Elsevier B.V. All rights reserved. 2011 Journal Article http://hdl.handle.net/20.500.11937/20198 10.1016/j.jallcom.2010.12.058 Elsevier B.V. restricted
spellingShingle Cui, Z.
Ye, R.
Deng, D.
Hua, Y.
Zhao, S.
Jia, Guohua
Li, C.
Xu, S.
Eu2+/Sm3+ ions co-doped white light luminescence SrSiO3 glass-ceramics phosphor for White LED
title Eu2+/Sm3+ ions co-doped white light luminescence SrSiO3 glass-ceramics phosphor for White LED
title_full Eu2+/Sm3+ ions co-doped white light luminescence SrSiO3 glass-ceramics phosphor for White LED
title_fullStr Eu2+/Sm3+ ions co-doped white light luminescence SrSiO3 glass-ceramics phosphor for White LED
title_full_unstemmed Eu2+/Sm3+ ions co-doped white light luminescence SrSiO3 glass-ceramics phosphor for White LED
title_short Eu2+/Sm3+ ions co-doped white light luminescence SrSiO3 glass-ceramics phosphor for White LED
title_sort eu2+/sm3+ ions co-doped white light luminescence srsio3 glass-ceramics phosphor for white led
url http://hdl.handle.net/20.500.11937/20198