The Thermodynamic Hydrate Difference Rule (HDR) Applied to Salts of Carbon-Containing Oxyacid Salts and Their Hydrates: Materials at the Inorganic-Organic Interface
The thermodynamic hydrate difference rule (HDR) has previously been explored largely within the compass of inorganic solids. In this paper we extend its range by studying its application to carbon-containing oxyacid salts, which may be regarded as borderline hydrate-forming inorganic or organic mate...
| Main Authors: | , , |
|---|---|
| Format: | Journal Article |
| Published: |
American Chemical Society
2010
|
| Online Access: | http://hdl.handle.net/20.500.11937/20031 |
| _version_ | 1848750196146569216 |
|---|---|
| author | Jenkins, H. Glasser, Leslie Liebman, J. |
| author_facet | Jenkins, H. Glasser, Leslie Liebman, J. |
| author_sort | Jenkins, H. |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | The thermodynamic hydrate difference rule (HDR) has previously been explored largely within the compass of inorganic solids. In this paper we extend its range by studying its application to carbon-containing oxyacid salts, which may be regarded as borderline hydrate-forming inorganic or organic material. We study in detail standard thermodynamic data as it appears in the National Bureau of Standards (NBS) tabulation for formate, carbonate, acetate, glycolate, and oxalate salt hydrates, finding the HDR to apply equally as well to these materials as it does to salts with solely inorganic parents. We use the resulting constants to predict thermodynamic quantities for some parent salts. |
| first_indexed | 2025-11-14T07:32:59Z |
| format | Journal Article |
| id | curtin-20.500.11937-20031 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T07:32:59Z |
| publishDate | 2010 |
| publisher | American Chemical Society |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-200312017-09-13T15:58:24Z The Thermodynamic Hydrate Difference Rule (HDR) Applied to Salts of Carbon-Containing Oxyacid Salts and Their Hydrates: Materials at the Inorganic-Organic Interface Jenkins, H. Glasser, Leslie Liebman, J. The thermodynamic hydrate difference rule (HDR) has previously been explored largely within the compass of inorganic solids. In this paper we extend its range by studying its application to carbon-containing oxyacid salts, which may be regarded as borderline hydrate-forming inorganic or organic material. We study in detail standard thermodynamic data as it appears in the National Bureau of Standards (NBS) tabulation for formate, carbonate, acetate, glycolate, and oxalate salt hydrates, finding the HDR to apply equally as well to these materials as it does to salts with solely inorganic parents. We use the resulting constants to predict thermodynamic quantities for some parent salts. 2010 Journal Article http://hdl.handle.net/20.500.11937/20031 10.1021/je100543c American Chemical Society restricted |
| spellingShingle | Jenkins, H. Glasser, Leslie Liebman, J. The Thermodynamic Hydrate Difference Rule (HDR) Applied to Salts of Carbon-Containing Oxyacid Salts and Their Hydrates: Materials at the Inorganic-Organic Interface |
| title | The Thermodynamic Hydrate Difference Rule (HDR) Applied to Salts of Carbon-Containing Oxyacid Salts and Their Hydrates: Materials at the Inorganic-Organic Interface |
| title_full | The Thermodynamic Hydrate Difference Rule (HDR) Applied to Salts of Carbon-Containing Oxyacid Salts and Their Hydrates: Materials at the Inorganic-Organic Interface |
| title_fullStr | The Thermodynamic Hydrate Difference Rule (HDR) Applied to Salts of Carbon-Containing Oxyacid Salts and Their Hydrates: Materials at the Inorganic-Organic Interface |
| title_full_unstemmed | The Thermodynamic Hydrate Difference Rule (HDR) Applied to Salts of Carbon-Containing Oxyacid Salts and Their Hydrates: Materials at the Inorganic-Organic Interface |
| title_short | The Thermodynamic Hydrate Difference Rule (HDR) Applied to Salts of Carbon-Containing Oxyacid Salts and Their Hydrates: Materials at the Inorganic-Organic Interface |
| title_sort | thermodynamic hydrate difference rule (hdr) applied to salts of carbon-containing oxyacid salts and their hydrates: materials at the inorganic-organic interface |
| url | http://hdl.handle.net/20.500.11937/20031 |