Dynamic neutron diffraction study of thermal stability and self-recovery in aluminium titanate

Aluminium titanate (Al2TiO5) is an excellent refractory and thermal shock resistant material dueto its relatively low thermal expansion coefficient and high melting point. However, Al2TiO5 unstableand undergoes a eutectoid-like decomposition to a-Al2O3 and TiO2 (rutile) at the temperature range of90...

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Main Authors: Low, It-Meng, Oo, Zeya
Other Authors: Sanjay Mathur
Format: Conference Paper
Published: American Ceramic Society 2010
Online Access:http://hdl.handle.net/20.500.11937/19968
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author Low, It-Meng
Oo, Zeya
author2 Sanjay Mathur
author_facet Sanjay Mathur
Low, It-Meng
Oo, Zeya
author_sort Low, It-Meng
building Curtin Institutional Repository
collection Online Access
description Aluminium titanate (Al2TiO5) is an excellent refractory and thermal shock resistant material dueto its relatively low thermal expansion coefficient and high melting point. However, Al2TiO5 unstableand undergoes a eutectoid-like decomposition to a-Al2O3 and TiO2 (rutile) at the temperature range of900-1280C. In this paper, we describe the use of high-temperature neutron diffraction to study (a) thephenomenon of self-recovery in decomposed Al2TiO5, and (b) the role of grain size on the rate ofisothermal decomposition at 1100C. It is shown that the process of decomposition in Al2TiO5 isreversible whereby self-recovery occurs readily when decomposed Al2TiO5 is re-heated above 1300C,and the rate of phase decomposition increases as the grain size decreases.
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spelling curtin-20.500.11937-199682023-01-13T07:56:30Z Dynamic neutron diffraction study of thermal stability and self-recovery in aluminium titanate Low, It-Meng Oo, Zeya Sanjay Mathur Tatsuki Ohji Aluminium titanate (Al2TiO5) is an excellent refractory and thermal shock resistant material dueto its relatively low thermal expansion coefficient and high melting point. However, Al2TiO5 unstableand undergoes a eutectoid-like decomposition to a-Al2O3 and TiO2 (rutile) at the temperature range of900-1280C. In this paper, we describe the use of high-temperature neutron diffraction to study (a) thephenomenon of self-recovery in decomposed Al2TiO5, and (b) the role of grain size on the rate ofisothermal decomposition at 1100C. It is shown that the process of decomposition in Al2TiO5 isreversible whereby self-recovery occurs readily when decomposed Al2TiO5 is re-heated above 1300C,and the rate of phase decomposition increases as the grain size decreases. 2010 Conference Paper http://hdl.handle.net/20.500.11937/19968 American Ceramic Society fulltext
spellingShingle Low, It-Meng
Oo, Zeya
Dynamic neutron diffraction study of thermal stability and self-recovery in aluminium titanate
title Dynamic neutron diffraction study of thermal stability and self-recovery in aluminium titanate
title_full Dynamic neutron diffraction study of thermal stability and self-recovery in aluminium titanate
title_fullStr Dynamic neutron diffraction study of thermal stability and self-recovery in aluminium titanate
title_full_unstemmed Dynamic neutron diffraction study of thermal stability and self-recovery in aluminium titanate
title_short Dynamic neutron diffraction study of thermal stability and self-recovery in aluminium titanate
title_sort dynamic neutron diffraction study of thermal stability and self-recovery in aluminium titanate
url http://hdl.handle.net/20.500.11937/19968