Roll-to-Roll Sputter Coating of Aluminum Cathodes for Large-Scale Fabrication of Organic Photovoltaic Devices
We report the demonstration of sputter-coated aluminum contacts directly onto P3HT:PCBM organic photovoltaic devices using a R2R process without detrimentally influencing the performance of the devices. The final sputtered devices do not require any protective buffer layers to produce efficient perf...
| Main Authors: | , , , , , , , , , |
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| Format: | Journal Article |
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WILEY-V C H VERLAG GMBH
2015
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| Online Access: | http://hdl.handle.net/20.500.11937/19547 |
| _version_ | 1848750063969370112 |
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| author | Griffith, M. Cooling, N. Vaughan, B. O'Donnell, Kane Al-Mudhaffer, M. Al-Ahmad, A. Noori, M. Almyahi, F. Belcher, W. Dastoor, P. |
| author_facet | Griffith, M. Cooling, N. Vaughan, B. O'Donnell, Kane Al-Mudhaffer, M. Al-Ahmad, A. Noori, M. Almyahi, F. Belcher, W. Dastoor, P. |
| author_sort | Griffith, M. |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | We report the demonstration of sputter-coated aluminum contacts directly onto P3HT:PCBM organic photovoltaic devices using a R2R process without detrimentally influencing the performance of the devices. The final sputtered devices do not require any protective buffer layers to produce efficient performance. Depth profiling analysis of sputtered films using X-ray photoelectron spectroscopy (XPS) indicated the presence of a 5–6 nm insulating oxide layer generated at the cathode interface for all sputtering target power densities greater than 1.4 W cm−2. The aluminum penetration into the P3HT:PCBM film was found to be consistent with the depth of this oxide layer, suggesting that aluminum penetration into the organic film is not the primary reason for performance limitations in sputtered devices. Introduction of thermally evaporated aluminum buffer layers prior to deposition of sputtered aluminum cathodes demonstrated that the performance of devices after annealing matched those of reference devices prepared with no sputtering for a buffer layer thickness of only 20 nm. Further analysis of the device J--V curves revealed an S-shaped kink prior to annealing, indicating that the major reason for the poor performance in sputtered devices was the introduction of a charge extraction barrier at the cathode, which was subsequently removed upon annealing.Rigorous removal of oxygen from the sputtering chamber prior to aluminum deposition onto the P3HT:PCBM active layer was subsequently observed to produce a device with an efficiency close to that of the thermally evaporated reference device without the requirement for evaporated buffer layers. The results presented here highlight a pathway towards an alternative R2R cathode fabrication technique that allows the highly efficient aluminum cathodes employed in small-scale devices to be transferred onto large-scale, flexible, and low-cost R2R printed organic electronic devices. |
| first_indexed | 2025-11-14T07:30:53Z |
| format | Journal Article |
| id | curtin-20.500.11937-19547 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T07:30:53Z |
| publishDate | 2015 |
| publisher | WILEY-V C H VERLAG GMBH |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-195472017-09-13T13:47:29Z Roll-to-Roll Sputter Coating of Aluminum Cathodes for Large-Scale Fabrication of Organic Photovoltaic Devices Griffith, M. Cooling, N. Vaughan, B. O'Donnell, Kane Al-Mudhaffer, M. Al-Ahmad, A. Noori, M. Almyahi, F. Belcher, W. Dastoor, P. We report the demonstration of sputter-coated aluminum contacts directly onto P3HT:PCBM organic photovoltaic devices using a R2R process without detrimentally influencing the performance of the devices. The final sputtered devices do not require any protective buffer layers to produce efficient performance. Depth profiling analysis of sputtered films using X-ray photoelectron spectroscopy (XPS) indicated the presence of a 5–6 nm insulating oxide layer generated at the cathode interface for all sputtering target power densities greater than 1.4 W cm−2. The aluminum penetration into the P3HT:PCBM film was found to be consistent with the depth of this oxide layer, suggesting that aluminum penetration into the organic film is not the primary reason for performance limitations in sputtered devices. Introduction of thermally evaporated aluminum buffer layers prior to deposition of sputtered aluminum cathodes demonstrated that the performance of devices after annealing matched those of reference devices prepared with no sputtering for a buffer layer thickness of only 20 nm. Further analysis of the device J--V curves revealed an S-shaped kink prior to annealing, indicating that the major reason for the poor performance in sputtered devices was the introduction of a charge extraction barrier at the cathode, which was subsequently removed upon annealing.Rigorous removal of oxygen from the sputtering chamber prior to aluminum deposition onto the P3HT:PCBM active layer was subsequently observed to produce a device with an efficiency close to that of the thermally evaporated reference device without the requirement for evaporated buffer layers. The results presented here highlight a pathway towards an alternative R2R cathode fabrication technique that allows the highly efficient aluminum cathodes employed in small-scale devices to be transferred onto large-scale, flexible, and low-cost R2R printed organic electronic devices. 2015 Journal Article http://hdl.handle.net/20.500.11937/19547 10.1002/ente.201402174 WILEY-V C H VERLAG GMBH restricted |
| spellingShingle | Griffith, M. Cooling, N. Vaughan, B. O'Donnell, Kane Al-Mudhaffer, M. Al-Ahmad, A. Noori, M. Almyahi, F. Belcher, W. Dastoor, P. Roll-to-Roll Sputter Coating of Aluminum Cathodes for Large-Scale Fabrication of Organic Photovoltaic Devices |
| title | Roll-to-Roll Sputter Coating of Aluminum Cathodes for Large-Scale Fabrication of Organic Photovoltaic Devices |
| title_full | Roll-to-Roll Sputter Coating of Aluminum Cathodes for Large-Scale Fabrication of Organic Photovoltaic Devices |
| title_fullStr | Roll-to-Roll Sputter Coating of Aluminum Cathodes for Large-Scale Fabrication of Organic Photovoltaic Devices |
| title_full_unstemmed | Roll-to-Roll Sputter Coating of Aluminum Cathodes for Large-Scale Fabrication of Organic Photovoltaic Devices |
| title_short | Roll-to-Roll Sputter Coating of Aluminum Cathodes for Large-Scale Fabrication of Organic Photovoltaic Devices |
| title_sort | roll-to-roll sputter coating of aluminum cathodes for large-scale fabrication of organic photovoltaic devices |
| url | http://hdl.handle.net/20.500.11937/19547 |