The golden ark: Arsenopyrite crystal plasticity and the retention of gold through high strain and metamorphism

Quantitative electron backscatter diffraction analysis and ion microprobe imaging of gold-rich arsenopyrites provide the first insights into the crystal plasticity and element mobility behaviour of arsenopyrites through metamorphism (340°-460° and 2 kbar). Remarkably, the gold-rich arsenopyrites rem...

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Bibliographic Details
Main Authors: Fougerouse, Denis, Micklethwaite, S., Halfpenny, Angela, Reddy, Steven, Cliff, J., Martin, L., Kilburn, M., Guagliardo, P., Ulrich, S.
Format: Journal Article
Published: Blackwell Publishing Ltd 2016
Online Access:http://hdl.handle.net/20.500.11937/18841
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Summary:Quantitative electron backscatter diffraction analysis and ion microprobe imaging of gold-rich arsenopyrites provide the first insights into the crystal plasticity and element mobility behaviour of arsenopyrites through metamorphism (340°-460° and 2 kbar). Remarkably, the gold-rich arsenopyrites remained structurally and chemically robust during high strain deformation. It was only during a superimposed lower strain deformation event, at a high angle to the preferred orientation of the arsenopyrites, that small amounts of crystal plasticity affected the arsenopyrites. During the low strain event, a dissolution-reprecipitation reaction resulted in loss of gold from the crystal lattice, facilitated by localised domains of recrystallisation, most likely due to fluid percolation along sub- and new grain boundaries. We suggest that the abundance and rheologically robust nature of gold-rich arsenopyrite in giant gold deposits, affected by greenschist-amphibolite metamorphism, is actually critical in the preservation of those deposits.