Synthesis and properties of the ivyanes: the parent 1,1-oligocyclopropanes

Practical syntheses of the first six members of the ivyane (1,1-oligocyclopropane) family of fundamentalhydrocarbons have been achieved from the cross-conjugated polyenes known as dendralenes. Evidencefor helical conformations in both the solid state and in solution is presented. [6]Ivyane exhibits...

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Main Authors: Bojase, G., Nguyen, T., Payne, Alan, Willis, A., Sherburn, M.
Format: Journal Article
Published: Royal Society of Chemistry 2011
Online Access:http://hdl.handle.net/20.500.11937/18621
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author Bojase, G.
Nguyen, T.
Payne, Alan
Willis, A.
Sherburn, M.
author_facet Bojase, G.
Nguyen, T.
Payne, Alan
Willis, A.
Sherburn, M.
author_sort Bojase, G.
building Curtin Institutional Repository
collection Online Access
description Practical syntheses of the first six members of the ivyane (1,1-oligocyclopropane) family of fundamentalhydrocarbons have been achieved from the cross-conjugated polyenes known as dendralenes. Evidencefor helical conformations in both the solid state and in solution is presented. [6]Ivyane exhibits one ofthe highest experimental heats of combustion recorded for a hydrocarbon. Ring-opening reactions ofivyanes furnish new and interesting structures that are difficult to access by conventional means.
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format Journal Article
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institution Curtin University Malaysia
institution_category Local University
last_indexed 2025-11-14T07:26:39Z
publishDate 2011
publisher Royal Society of Chemistry
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spelling curtin-20.500.11937-186212017-09-13T13:44:34Z Synthesis and properties of the ivyanes: the parent 1,1-oligocyclopropanes Bojase, G. Nguyen, T. Payne, Alan Willis, A. Sherburn, M. Practical syntheses of the first six members of the ivyane (1,1-oligocyclopropane) family of fundamentalhydrocarbons have been achieved from the cross-conjugated polyenes known as dendralenes. Evidencefor helical conformations in both the solid state and in solution is presented. [6]Ivyane exhibits one ofthe highest experimental heats of combustion recorded for a hydrocarbon. Ring-opening reactions ofivyanes furnish new and interesting structures that are difficult to access by conventional means. 2011 Journal Article http://hdl.handle.net/20.500.11937/18621 10.1039/c0sc00500b Royal Society of Chemistry restricted
spellingShingle Bojase, G.
Nguyen, T.
Payne, Alan
Willis, A.
Sherburn, M.
Synthesis and properties of the ivyanes: the parent 1,1-oligocyclopropanes
title Synthesis and properties of the ivyanes: the parent 1,1-oligocyclopropanes
title_full Synthesis and properties of the ivyanes: the parent 1,1-oligocyclopropanes
title_fullStr Synthesis and properties of the ivyanes: the parent 1,1-oligocyclopropanes
title_full_unstemmed Synthesis and properties of the ivyanes: the parent 1,1-oligocyclopropanes
title_short Synthesis and properties of the ivyanes: the parent 1,1-oligocyclopropanes
title_sort synthesis and properties of the ivyanes: the parent 1,1-oligocyclopropanes
url http://hdl.handle.net/20.500.11937/18621