Actinide coordination chemistry - a unique example of a homoleptic complex of nine-coordinate thorium(IV)

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Actinide coordination chemistry - a unique example of a homoleptic complex of nine-coordinate thorium(IV)

The dimethylsulfoxide (dmso) solvate of Th(IV) perchlorate is readily obtained from acidic aqueous Th(IV) solutions and has a formulation established from a single crystal structure determination of [Th(dmso-O)9](ClO4)4 . 4dmso; triclinic, P1, a = 12:4811(8)A, b = 12:4879(8)A, c = 23:969(2)A, a = 94...

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Bibliographic Details
Main Authors:	Harrowfield, J., Ogden, Mark, Skelton, B., White, A.
Format:	Journal Article
Published:	Elsevier 2004
Subjects:	Homoleptic dmso complex Thorium Nine-coordination Crystal structure
Online Access:	http://hdl.handle.net/20.500.11937/18415

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