Actinide coordination chemistry - a unique example of a homoleptic complex of nine-coordinate thorium(IV)
The dimethylsulfoxide (dmso) solvate of Th(IV) perchlorate is readily obtained from acidic aqueous Th(IV) solutions and has a formulation established from a single crystal structure determination of [Th(dmso-O)9](ClO4)4 . 4dmso; triclinic, P1, a = 12:4811(8)A, b = 12:4879(8)A, c = 23:969(2)A, a = 94...
| Main Authors: | , , , |
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| Format: | Journal Article |
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Elsevier
2004
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| Online Access: | http://hdl.handle.net/20.500.11937/18415 |
| _version_ | 1848749738115989504 |
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| author | Harrowfield, J. Ogden, Mark Skelton, B. White, A. |
| author_facet | Harrowfield, J. Ogden, Mark Skelton, B. White, A. |
| author_sort | Harrowfield, J. |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | The dimethylsulfoxide (dmso) solvate of Th(IV) perchlorate is readily obtained from acidic aqueous Th(IV) solutions and has a formulation established from a single crystal structure determination of [Th(dmso-O)9](ClO4)4 . 4dmso; triclinic, P1, a = 12:4811(8)A, b = 12:4879(8)A, c = 23:969(2)A, a = 94:684(1), b = 95:823(1), y = 119:347(1). The primary coordination sphere of the Th is of tricapped trigonal prismatic form, with the symmetry of the [Th(dmso-O)9] entity being close to C3h. |
| first_indexed | 2025-11-14T07:25:42Z |
| format | Journal Article |
| id | curtin-20.500.11937-18415 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T07:25:42Z |
| publishDate | 2004 |
| publisher | Elsevier |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-184152018-10-01T04:25:51Z Actinide coordination chemistry - a unique example of a homoleptic complex of nine-coordinate thorium(IV) Harrowfield, J. Ogden, Mark Skelton, B. White, A. Homoleptic dmso complex Thorium Nine-coordination Crystal structure The dimethylsulfoxide (dmso) solvate of Th(IV) perchlorate is readily obtained from acidic aqueous Th(IV) solutions and has a formulation established from a single crystal structure determination of [Th(dmso-O)9](ClO4)4 . 4dmso; triclinic, P1, a = 12:4811(8)A, b = 12:4879(8)A, c = 23:969(2)A, a = 94:684(1), b = 95:823(1), y = 119:347(1). The primary coordination sphere of the Th is of tricapped trigonal prismatic form, with the symmetry of the [Th(dmso-O)9] entity being close to C3h. 2004 Journal Article http://hdl.handle.net/20.500.11937/18415 10.1016/j.ica.2004.01.030 Elsevier restricted |
| spellingShingle | Homoleptic dmso complex Thorium Nine-coordination Crystal structure Harrowfield, J. Ogden, Mark Skelton, B. White, A. Actinide coordination chemistry - a unique example of a homoleptic complex of nine-coordinate thorium(IV) |
| title | Actinide coordination chemistry - a unique example of a homoleptic complex of nine-coordinate thorium(IV) |
| title_full | Actinide coordination chemistry - a unique example of a homoleptic complex of nine-coordinate thorium(IV) |
| title_fullStr | Actinide coordination chemistry - a unique example of a homoleptic complex of nine-coordinate thorium(IV) |
| title_full_unstemmed | Actinide coordination chemistry - a unique example of a homoleptic complex of nine-coordinate thorium(IV) |
| title_short | Actinide coordination chemistry - a unique example of a homoleptic complex of nine-coordinate thorium(IV) |
| title_sort | actinide coordination chemistry - a unique example of a homoleptic complex of nine-coordinate thorium(iv) |
| topic | Homoleptic dmso complex Thorium Nine-coordination Crystal structure |
| url | http://hdl.handle.net/20.500.11937/18415 |