Silver and Palladium Complexes of a Bis(benzimidazolin-2-ylidene)pyridine Pincer Ligand
Reaction of 2,6-bis(3-butylbenzimidazol-1-ium)pyridine dibromide with silVer oxide affords a dinuclear complex of the type [L2Ag2]2+ [L ) 2,6-bis(3-butylbenzimidazolin-2-ylidene)pyridine]. 1H NMR spectroscopic studies suggest that the dinuclear structure is also present in solution. Transmetalationo...
| Main Authors: | , , , , |
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| Format: | Journal Article |
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ACS Publications
2009
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| Online Access: | http://pubs.acs.org/doi/full/10.1021/om801144m http://hdl.handle.net/20.500.11937/18254 |
| _version_ | 1848749691797241856 |
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| author | Brown, David Nealon, Gareth Simpson, P. Skelton, B. Wang, Zhisen |
| author_facet | Brown, David Nealon, Gareth Simpson, P. Skelton, B. Wang, Zhisen |
| author_sort | Brown, David |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | Reaction of 2,6-bis(3-butylbenzimidazol-1-ium)pyridine dibromide with silVer oxide affords a dinuclear complex of the type [L2Ag2]2+ [L ) 2,6-bis(3-butylbenzimidazolin-2-ylidene)pyridine]. 1H NMR spectroscopic studies suggest that the dinuclear structure is also present in solution. Transmetalationof the silVer-NHC complex with PdCl2(CH3CN)2 yields a mononuclear palladium complex of the type [LPdCl]+, with a chelating C,N,C pincer ligand. |
| first_indexed | 2025-11-14T07:24:58Z |
| format | Journal Article |
| id | curtin-20.500.11937-18254 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T07:24:58Z |
| publishDate | 2009 |
| publisher | ACS Publications |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-182542019-02-19T05:35:12Z Silver and Palladium Complexes of a Bis(benzimidazolin-2-ylidene)pyridine Pincer Ligand Brown, David Nealon, Gareth Simpson, P. Skelton, B. Wang, Zhisen Reaction of 2,6-bis(3-butylbenzimidazol-1-ium)pyridine dibromide with silVer oxide affords a dinuclear complex of the type [L2Ag2]2+ [L ) 2,6-bis(3-butylbenzimidazolin-2-ylidene)pyridine]. 1H NMR spectroscopic studies suggest that the dinuclear structure is also present in solution. Transmetalationof the silVer-NHC complex with PdCl2(CH3CN)2 yields a mononuclear palladium complex of the type [LPdCl]+, with a chelating C,N,C pincer ligand. 2009 Journal Article http://hdl.handle.net/20.500.11937/18254 http://pubs.acs.org/doi/full/10.1021/om801144m http://pubs.acs.org/toc/orgnd7/28/6 ACS Publications fulltext |
| spellingShingle | Brown, David Nealon, Gareth Simpson, P. Skelton, B. Wang, Zhisen Silver and Palladium Complexes of a Bis(benzimidazolin-2-ylidene)pyridine Pincer Ligand |
| title | Silver and Palladium Complexes of a Bis(benzimidazolin-2-ylidene)pyridine Pincer Ligand |
| title_full | Silver and Palladium Complexes of a Bis(benzimidazolin-2-ylidene)pyridine Pincer Ligand |
| title_fullStr | Silver and Palladium Complexes of a Bis(benzimidazolin-2-ylidene)pyridine Pincer Ligand |
| title_full_unstemmed | Silver and Palladium Complexes of a Bis(benzimidazolin-2-ylidene)pyridine Pincer Ligand |
| title_short | Silver and Palladium Complexes of a Bis(benzimidazolin-2-ylidene)pyridine Pincer Ligand |
| title_sort | silver and palladium complexes of a bis(benzimidazolin-2-ylidene)pyridine pincer ligand |
| url | http://pubs.acs.org/doi/full/10.1021/om801144m http://pubs.acs.org/doi/full/10.1021/om801144m http://hdl.handle.net/20.500.11937/18254 |