A novel approach to synthesize ultrasmall Cu doped Zn-In-Se nanocrystal emitters in a colloidal system

A facile phosphine-free approach is presented to prepare Cu doped ternary Zn–In–Se nanocrystals with high performance photoluminescence. By doping during nucleation stage, Cu dopant serving as a dominative emission centre was introduced into a weak fluorescence ternary system to modify the emission...

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Main Authors: Ke, J., Li, Xin Yong, Zhao, Q., Shi, Y., Chen, G.
Format: Journal Article
Published: Royal Society of Chemistry 2014
Online Access:http://hdl.handle.net/20.500.11937/17863
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author Ke, J.
Li, Xin Yong
Zhao, Q.
Shi, Y.
Chen, G.
author_facet Ke, J.
Li, Xin Yong
Zhao, Q.
Shi, Y.
Chen, G.
author_sort Ke, J.
building Curtin Institutional Repository
collection Online Access
description A facile phosphine-free approach is presented to prepare Cu doped ternary Zn–In–Se nanocrystals with high performance photoluminescence. By doping during nucleation stage, Cu dopant serving as a dominative emission centre was introduced into a weak fluorescence ternary system to modify the emission path. As a result of varying the ratios of zinc to indium, emission of the products is tunable ranging from 620 to 545 nm and a photoluminescence quantum yield of up to 20%. Meanwhile, a large Stokes shift of 467 meV is achieved.
first_indexed 2025-11-14T07:23:12Z
format Journal Article
id curtin-20.500.11937-17863
institution Curtin University Malaysia
institution_category Local University
last_indexed 2025-11-14T07:23:12Z
publishDate 2014
publisher Royal Society of Chemistry
recordtype eprints
repository_type Digital Repository
spelling curtin-20.500.11937-178632017-09-13T13:36:45Z A novel approach to synthesize ultrasmall Cu doped Zn-In-Se nanocrystal emitters in a colloidal system Ke, J. Li, Xin Yong Zhao, Q. Shi, Y. Chen, G. A facile phosphine-free approach is presented to prepare Cu doped ternary Zn–In–Se nanocrystals with high performance photoluminescence. By doping during nucleation stage, Cu dopant serving as a dominative emission centre was introduced into a weak fluorescence ternary system to modify the emission path. As a result of varying the ratios of zinc to indium, emission of the products is tunable ranging from 620 to 545 nm and a photoluminescence quantum yield of up to 20%. Meanwhile, a large Stokes shift of 467 meV is achieved. 2014 Journal Article http://hdl.handle.net/20.500.11937/17863 10.1039/c3nr06168j Royal Society of Chemistry restricted
spellingShingle Ke, J.
Li, Xin Yong
Zhao, Q.
Shi, Y.
Chen, G.
A novel approach to synthesize ultrasmall Cu doped Zn-In-Se nanocrystal emitters in a colloidal system
title A novel approach to synthesize ultrasmall Cu doped Zn-In-Se nanocrystal emitters in a colloidal system
title_full A novel approach to synthesize ultrasmall Cu doped Zn-In-Se nanocrystal emitters in a colloidal system
title_fullStr A novel approach to synthesize ultrasmall Cu doped Zn-In-Se nanocrystal emitters in a colloidal system
title_full_unstemmed A novel approach to synthesize ultrasmall Cu doped Zn-In-Se nanocrystal emitters in a colloidal system
title_short A novel approach to synthesize ultrasmall Cu doped Zn-In-Se nanocrystal emitters in a colloidal system
title_sort novel approach to synthesize ultrasmall cu doped zn-in-se nanocrystal emitters in a colloidal system
url http://hdl.handle.net/20.500.11937/17863