Optimization of click chemistry of ferrocene derivatives on acetylene-functionalized silicon(100) surfaces
The optimization of the reaction conditions for copper-catalyzed azide-alkyne ,click- cyclo-addition reactions used to covalently confine substituted ferrocene derivatives on passivated silicon(100) surfaces is reported. Variations in the observed reaction yields and the extent of surface contaminat...
| Main Authors: | , , , |
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| Format: | Journal Article |
| Published: |
Wiley - VCH Verlag GmbH & Co. KGaA
2008
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| Online Access: | http://hdl.handle.net/20.500.11937/17838 |
| _version_ | 1848749573509480448 |
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| author | Ciampi, Simone Le Saux, G. Harper, J. Gooding, J. |
| author_facet | Ciampi, Simone Le Saux, G. Harper, J. Gooding, J. |
| author_sort | Ciampi, Simone |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | The optimization of the reaction conditions for copper-catalyzed azide-alkyne ,click- cyclo-addition reactions used to covalently confine substituted ferrocene derivatives on passivated silicon(100) surfaces is reported. Variations in the observed reaction yields and the extent of surface contamination as a function of the source of the copper catalyst and the solvent system used in the ,click- procedure were evaluated spectroscopically. The electronic communication between the ferrocene centre and the underlying semiconductor surface was investigated by means of cyclic voltammetry and found to be consistent with that expected for a well-behaved and robust redox interface. © 2008 Wiley-VCH Verlag GmbH&Co. KGaA. |
| first_indexed | 2025-11-14T07:23:05Z |
| format | Journal Article |
| id | curtin-20.500.11937-17838 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T07:23:05Z |
| publishDate | 2008 |
| publisher | Wiley - VCH Verlag GmbH & Co. KGaA |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-178382017-09-13T15:44:54Z Optimization of click chemistry of ferrocene derivatives on acetylene-functionalized silicon(100) surfaces Ciampi, Simone Le Saux, G. Harper, J. Gooding, J. The optimization of the reaction conditions for copper-catalyzed azide-alkyne ,click- cyclo-addition reactions used to covalently confine substituted ferrocene derivatives on passivated silicon(100) surfaces is reported. Variations in the observed reaction yields and the extent of surface contamination as a function of the source of the copper catalyst and the solvent system used in the ,click- procedure were evaluated spectroscopically. The electronic communication between the ferrocene centre and the underlying semiconductor surface was investigated by means of cyclic voltammetry and found to be consistent with that expected for a well-behaved and robust redox interface. © 2008 Wiley-VCH Verlag GmbH&Co. KGaA. 2008 Journal Article http://hdl.handle.net/20.500.11937/17838 10.1002/elan.200804241 Wiley - VCH Verlag GmbH & Co. KGaA restricted |
| spellingShingle | Ciampi, Simone Le Saux, G. Harper, J. Gooding, J. Optimization of click chemistry of ferrocene derivatives on acetylene-functionalized silicon(100) surfaces |
| title | Optimization of click chemistry of ferrocene derivatives on acetylene-functionalized silicon(100) surfaces |
| title_full | Optimization of click chemistry of ferrocene derivatives on acetylene-functionalized silicon(100) surfaces |
| title_fullStr | Optimization of click chemistry of ferrocene derivatives on acetylene-functionalized silicon(100) surfaces |
| title_full_unstemmed | Optimization of click chemistry of ferrocene derivatives on acetylene-functionalized silicon(100) surfaces |
| title_short | Optimization of click chemistry of ferrocene derivatives on acetylene-functionalized silicon(100) surfaces |
| title_sort | optimization of click chemistry of ferrocene derivatives on acetylene-functionalized silicon(100) surfaces |
| url | http://hdl.handle.net/20.500.11937/17838 |