High yield and low-cost ball milling synthesis of nano-flake Si@SiO2 with small crystalline grains and abundant grain boundaries as a superior anode for Li-ion batteries
A high yield and low-cost high-energy wet ball milling method is used for producing nano-flake Si@SiO2 as an anode material for Li-ion batteries. After a two-step ball milling (coarse milling and fine milling) process, the irregular plate-like micrometric Si (average particle size is 27.4 μm) is fra...
| Main Authors: | , , , , , |
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| Format: | Journal Article |
| Published: |
Elsevier B.V.
2015
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| Online Access: | http://hdl.handle.net/20.500.11937/17805 |
| Summary: | A high yield and low-cost high-energy wet ball milling method is used for producing nano-flake Si@SiO2 as an anode material for Li-ion batteries. After a two-step ball milling (coarse milling and fine milling) process, the irregular plate-like micrometric Si (average particle size is 27.4 μm) is fractured into nano-flake Si@SiO2 (average particle size is 154.8 nm) with small crystalline grains and abundant grain boundaries. Due to the significant changes of the prepared nano-flake Si@SiO2 in the surface composition, particle size and crystal structure, the ball milled Si shows better electrochemical performance compared with the as-received micrometric Si. And the fine milled Si shows the best electrochemical properties with a high initial coulombic efficiency of 84.6% and a specific capacity of 1920.4 mA h g−1 at a current density of 100 mA g−1 after 100 cycles. |
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