Thiol-reactive Passerini-methacrylates and Polymorphic Surface Functional Soft Matter Nanoparticles via Ethanolic RAFT Dispersion Polymerization and Post-polymerization Modification
RAFT dispersion polymerization (RAFTDP) is used to prepare reactive nanoparticles via the incorporation of Passerini-derived methacrylic comonomers containing pentafluorophenyl (PFP) groups. Copolymerization of 2-(dimethylamino)ethyl methacrylate with a Passerini comonomer gives copolymers suitable...
| Main Authors: | , , , |
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| Format: | Journal Article |
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R S C Publications
2015
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| Online Access: | http://hdl.handle.net/20.500.11937/17563 |
| _version_ | 1848749499019689984 |
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| author | Pei, Y. Noy, J. Roth, P. Lowe, Andrew |
| author_facet | Pei, Y. Noy, J. Roth, P. Lowe, Andrew |
| author_sort | Pei, Y. |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | RAFT dispersion polymerization (RAFTDP) is used to prepare reactive nanoparticles via the incorporation of Passerini-derived methacrylic comonomers containing pentafluorophenyl (PFP) groups. Copolymerization of 2-(dimethylamino)ethyl methacrylate with a Passerini comonomer gives copolymers suitable as macro-CTAs for ethanolic RAFTDP of 3-phenylpropyl methacrylate. Reaction of the PFP residues with functional thiols offers an approach for preparing surface modified nanoparticles. |
| first_indexed | 2025-11-14T07:21:54Z |
| format | Journal Article |
| id | curtin-20.500.11937-17563 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T07:21:54Z |
| publishDate | 2015 |
| publisher | R S C Publications |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-175632017-09-13T15:43:06Z Thiol-reactive Passerini-methacrylates and Polymorphic Surface Functional Soft Matter Nanoparticles via Ethanolic RAFT Dispersion Polymerization and Post-polymerization Modification Pei, Y. Noy, J. Roth, P. Lowe, Andrew RAFT dispersion polymerization (RAFTDP) is used to prepare reactive nanoparticles via the incorporation of Passerini-derived methacrylic comonomers containing pentafluorophenyl (PFP) groups. Copolymerization of 2-(dimethylamino)ethyl methacrylate with a Passerini comonomer gives copolymers suitable as macro-CTAs for ethanolic RAFTDP of 3-phenylpropyl methacrylate. Reaction of the PFP residues with functional thiols offers an approach for preparing surface modified nanoparticles. 2015 Journal Article http://hdl.handle.net/20.500.11937/17563 10.1039/c4py01558d R S C Publications restricted |
| spellingShingle | Pei, Y. Noy, J. Roth, P. Lowe, Andrew Thiol-reactive Passerini-methacrylates and Polymorphic Surface Functional Soft Matter Nanoparticles via Ethanolic RAFT Dispersion Polymerization and Post-polymerization Modification |
| title | Thiol-reactive Passerini-methacrylates and Polymorphic Surface Functional Soft Matter Nanoparticles via Ethanolic RAFT Dispersion Polymerization and Post-polymerization Modification |
| title_full | Thiol-reactive Passerini-methacrylates and Polymorphic Surface Functional Soft Matter Nanoparticles via Ethanolic RAFT Dispersion Polymerization and Post-polymerization Modification |
| title_fullStr | Thiol-reactive Passerini-methacrylates and Polymorphic Surface Functional Soft Matter Nanoparticles via Ethanolic RAFT Dispersion Polymerization and Post-polymerization Modification |
| title_full_unstemmed | Thiol-reactive Passerini-methacrylates and Polymorphic Surface Functional Soft Matter Nanoparticles via Ethanolic RAFT Dispersion Polymerization and Post-polymerization Modification |
| title_short | Thiol-reactive Passerini-methacrylates and Polymorphic Surface Functional Soft Matter Nanoparticles via Ethanolic RAFT Dispersion Polymerization and Post-polymerization Modification |
| title_sort | thiol-reactive passerini-methacrylates and polymorphic surface functional soft matter nanoparticles via ethanolic raft dispersion polymerization and post-polymerization modification |
| url | http://hdl.handle.net/20.500.11937/17563 |