7-(4-Fluorobenzylamino)-2-phenyl-1,2,4-triazolo[1,5-a][1,3,5]triazin-5-amine methanol disolvate
THe 1,2,4-triazolo[1,5-a][1,3,5]triazine system in the title compound, C17H14FN7.2CH3OH, is essentially planar, with an r.m.s. deviation of 0.0215 A. The attached phenyl ring lies almost in the mean plane of the heterocyclic core [dihedral angle = 3.56 (4)deg]. In the crystal, centrosymmetric invers...
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| Format: | Journal Article |
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Blackwell Munksgaard
2011
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| Online Access: | http://hdl.handle.net/20.500.11937/17517 |
| _version_ | 1848749487313387520 |
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| author | Dolzhenko, Anton Tan, G. Koh, L. Dolzhenko, A. Chui, W. |
| author_facet | Dolzhenko, Anton Tan, G. Koh, L. Dolzhenko, A. Chui, W. |
| author_sort | Dolzhenko, Anton |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | THe 1,2,4-triazolo[1,5-a][1,3,5]triazine system in the title compound, C17H14FN7.2CH3OH, is essentially planar, with an r.m.s. deviation of 0.0215 A. The attached phenyl ring lies almost in the mean plane of the heterocyclic core [dihedral angle = 3.56 (4)deg]. In the crystal, centrosymmetric inversion dimers connected via intermolecular N=H...N hydrogen bonds between H atom of the primary amino group and the triazine N atom [R22(8) graph-set motif] form sheets parallel to (010). A second set of dimers connected via N=H...F hydrogen bonds between the other H atom of the primaryamino group and the F atom forms an R22(24) graph-set motif linking the sheets. Methanol solvent molecules are packed in channels running along the [010] direction. |
| first_indexed | 2025-11-14T07:21:43Z |
| format | Journal Article |
| id | curtin-20.500.11937-17517 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T07:21:43Z |
| publishDate | 2011 |
| publisher | Blackwell Munksgaard |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-175172017-09-13T15:44:54Z 7-(4-Fluorobenzylamino)-2-phenyl-1,2,4-triazolo[1,5-a][1,3,5]triazin-5-amine methanol disolvate Dolzhenko, Anton Tan, G. Koh, L. Dolzhenko, A. Chui, W. 5-azapurines solvate triazines. triazoles crystallography THe 1,2,4-triazolo[1,5-a][1,3,5]triazine system in the title compound, C17H14FN7.2CH3OH, is essentially planar, with an r.m.s. deviation of 0.0215 A. The attached phenyl ring lies almost in the mean plane of the heterocyclic core [dihedral angle = 3.56 (4)deg]. In the crystal, centrosymmetric inversion dimers connected via intermolecular N=H...N hydrogen bonds between H atom of the primary amino group and the triazine N atom [R22(8) graph-set motif] form sheets parallel to (010). A second set of dimers connected via N=H...F hydrogen bonds between the other H atom of the primaryamino group and the F atom forms an R22(24) graph-set motif linking the sheets. Methanol solvent molecules are packed in channels running along the [010] direction. 2011 Journal Article http://hdl.handle.net/20.500.11937/17517 10.1107/S1600536811014176 Blackwell Munksgaard fulltext |
| spellingShingle | 5-azapurines solvate triazines. triazoles crystallography Dolzhenko, Anton Tan, G. Koh, L. Dolzhenko, A. Chui, W. 7-(4-Fluorobenzylamino)-2-phenyl-1,2,4-triazolo[1,5-a][1,3,5]triazin-5-amine methanol disolvate |
| title | 7-(4-Fluorobenzylamino)-2-phenyl-1,2,4-triazolo[1,5-a][1,3,5]triazin-5-amine methanol disolvate |
| title_full | 7-(4-Fluorobenzylamino)-2-phenyl-1,2,4-triazolo[1,5-a][1,3,5]triazin-5-amine methanol disolvate |
| title_fullStr | 7-(4-Fluorobenzylamino)-2-phenyl-1,2,4-triazolo[1,5-a][1,3,5]triazin-5-amine methanol disolvate |
| title_full_unstemmed | 7-(4-Fluorobenzylamino)-2-phenyl-1,2,4-triazolo[1,5-a][1,3,5]triazin-5-amine methanol disolvate |
| title_short | 7-(4-Fluorobenzylamino)-2-phenyl-1,2,4-triazolo[1,5-a][1,3,5]triazin-5-amine methanol disolvate |
| title_sort | 7-(4-fluorobenzylamino)-2-phenyl-1,2,4-triazolo[1,5-a][1,3,5]triazin-5-amine methanol disolvate |
| topic | 5-azapurines solvate triazines. triazoles crystallography |
| url | http://hdl.handle.net/20.500.11937/17517 |