Array of water|room temperature ionic liquid micro-interfaces
Cyclic Voltammetry and AC Voltammetry were used to characterise the micro-interface array between water and a commercially available room temperature ionic liquid (RTIL) trihexyltetradecylphosphonium tris (pentafluoroethyl)trifluorophosphate ([P14,6,6,6][FAP]) for the first time. The interface array...
| Main Authors: | , |
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| Format: | Journal Article |
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Elsevier
2011
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| Online Access: | http://hdl.handle.net/20.500.11937/17260 |
| _version_ | 1848749417463545856 |
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| author | Silvester, Debbie Arrigan, Damien |
| author_facet | Silvester, Debbie Arrigan, Damien |
| author_sort | Silvester, Debbie |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | Cyclic Voltammetry and AC Voltammetry were used to characterise the micro-interface array between water and a commercially available room temperature ionic liquid (RTIL) trihexyltetradecylphosphonium tris (pentafluoroethyl)trifluorophosphate ([P14,6,6,6][FAP]) for the first time. The interface array was formed within the micropores of a silicon chip membrane (30 pores and 23 m diameter). The polarisable potential window and capacitance curves were recorded, and the transfers of three cations (tetraalkylammoniums) and three anions (tetraphenylborate, hexafluorophosphate and tetrafluoroborate) across the interface were studied. The shapes of the voltammograms revealed that the RTIL filled the pores and that the interface was located at/near the pore mouths. This is the first report of voltammetry at an array of water|RTIL microinterfaces, rather than at a single interface or porous polymer supported-interface. This work is particularly relevant to the sensing/extraction of redox-inactive ions. |
| first_indexed | 2025-11-14T07:20:36Z |
| format | Journal Article |
| id | curtin-20.500.11937-17260 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T07:20:36Z |
| publishDate | 2011 |
| publisher | Elsevier |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-172602019-02-19T04:25:44Z Array of water|room temperature ionic liquid micro-interfaces Silvester, Debbie Arrigan, Damien Ion transfer Water/ionic liquid interface Microinterface Voltammetry Room temperature ionic liquid Cyclic Voltammetry and AC Voltammetry were used to characterise the micro-interface array between water and a commercially available room temperature ionic liquid (RTIL) trihexyltetradecylphosphonium tris (pentafluoroethyl)trifluorophosphate ([P14,6,6,6][FAP]) for the first time. The interface array was formed within the micropores of a silicon chip membrane (30 pores and 23 m diameter). The polarisable potential window and capacitance curves were recorded, and the transfers of three cations (tetraalkylammoniums) and three anions (tetraphenylborate, hexafluorophosphate and tetrafluoroborate) across the interface were studied. The shapes of the voltammograms revealed that the RTIL filled the pores and that the interface was located at/near the pore mouths. This is the first report of voltammetry at an array of water|RTIL microinterfaces, rather than at a single interface or porous polymer supported-interface. This work is particularly relevant to the sensing/extraction of redox-inactive ions. 2011 Journal Article http://hdl.handle.net/20.500.11937/17260 10.1016/j.elecom.2011.02.025 Elsevier fulltext |
| spellingShingle | Ion transfer Water/ionic liquid interface Microinterface Voltammetry Room temperature ionic liquid Silvester, Debbie Arrigan, Damien Array of water|room temperature ionic liquid micro-interfaces |
| title | Array of water|room temperature ionic liquid micro-interfaces |
| title_full | Array of water|room temperature ionic liquid micro-interfaces |
| title_fullStr | Array of water|room temperature ionic liquid micro-interfaces |
| title_full_unstemmed | Array of water|room temperature ionic liquid micro-interfaces |
| title_short | Array of water|room temperature ionic liquid micro-interfaces |
| title_sort | array of water|room temperature ionic liquid micro-interfaces |
| topic | Ion transfer Water/ionic liquid interface Microinterface Voltammetry Room temperature ionic liquid |
| url | http://hdl.handle.net/20.500.11937/17260 |