Synthesis and structural studies of a lanthanide complex of a calix[4]arene tris-amide
The coordination chemistry of amide-substituted calixarenes is reviewed. The synthesis of a gadolinium complex of a trisamide calix[4]arene is described, involving the reaction of 5,11,17,23-tetra-tert-butyl-24-hydroxy-26,27,28-tris(diethylcarbamoylmethoxy) calix[4]arene (L) with gadolinium picrate...
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| Format: | Journal Article |
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Elsevier SAS
2005
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| Online Access: | http://hdl.handle.net/20.500.11937/17105 |
| _version_ | 1848749368717344768 |
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| author | Ogden, Mark Skelton, B. White, A. |
| author_facet | Ogden, Mark Skelton, B. White, A. |
| author_sort | Ogden, Mark |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | The coordination chemistry of amide-substituted calixarenes is reviewed. The synthesis of a gadolinium complex of a trisamide calix[4]arene is described, involving the reaction of 5,11,17,23-tetra-tert-butyl-24-hydroxy-26,27,28-tris(diethylcarbamoylmethoxy) calix[4]arene (L) with gadolinium picrate dodecahydrate. Structural studies demonstrated that the complex can be formulated as [(pic-O)Gd{(L H)(EtOH)}](pic)2 EtOH. |
| first_indexed | 2025-11-14T07:19:50Z |
| format | Journal Article |
| id | curtin-20.500.11937-17105 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T07:19:50Z |
| publishDate | 2005 |
| publisher | Elsevier SAS |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-171052017-09-13T15:43:55Z Synthesis and structural studies of a lanthanide complex of a calix[4]arene tris-amide Ogden, Mark Skelton, B. White, A. Lanthanide Calixarene Crystal structure Picrate The coordination chemistry of amide-substituted calixarenes is reviewed. The synthesis of a gadolinium complex of a trisamide calix[4]arene is described, involving the reaction of 5,11,17,23-tetra-tert-butyl-24-hydroxy-26,27,28-tris(diethylcarbamoylmethoxy) calix[4]arene (L) with gadolinium picrate dodecahydrate. Structural studies demonstrated that the complex can be formulated as [(pic-O)Gd{(L H)(EtOH)}](pic)2 EtOH. 2005 Journal Article http://hdl.handle.net/20.500.11937/17105 10.1016/j.crci.2004.10.019 Elsevier SAS fulltext |
| spellingShingle | Lanthanide Calixarene Crystal structure Picrate Ogden, Mark Skelton, B. White, A. Synthesis and structural studies of a lanthanide complex of a calix[4]arene tris-amide |
| title | Synthesis and structural studies of a lanthanide complex of a calix[4]arene tris-amide |
| title_full | Synthesis and structural studies of a lanthanide complex of a calix[4]arene tris-amide |
| title_fullStr | Synthesis and structural studies of a lanthanide complex of a calix[4]arene tris-amide |
| title_full_unstemmed | Synthesis and structural studies of a lanthanide complex of a calix[4]arene tris-amide |
| title_short | Synthesis and structural studies of a lanthanide complex of a calix[4]arene tris-amide |
| title_sort | synthesis and structural studies of a lanthanide complex of a calix[4]arene tris-amide |
| topic | Lanthanide Calixarene Crystal structure Picrate |
| url | http://hdl.handle.net/20.500.11937/17105 |