Orbital Interaction and Electron Density Transfer in PdII([9]aneB2A)L2 Complexes: Theoretical Approaches

Orbital Interaction and Electron Density Transfer in PdII([9]aneB2A)L2 Complexes: Theoretical Approaches

The geometric structures of Pd-complexes {Pd([9]aneB2A)L2 and Pd([9]aneBAB)L2 where A = P, S; B = N; L = PH3, P(CH3)3, Cl−}, their selective orbital interaction towards equatorial or axial (soft A…Pd) coordination of macrocyclic [9]aneB2A tridentate to PdL2, and electron density transfer from the el...

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Bibliographic Details
Main Authors: Keum Kwak, Ock, Arooj, Mahreen, Yoon, Yong-Jin, Duck Jeong, Euh, Keun Park, Jong
Format: Journal Article
Published: M D P I AG 2013
Subjects:
geometric configuration
orbital interaction
steric and electronic effects
position selectivity
macrocyclic tridentate
Online Access:http://hdl.handle.net/20.500.11937/16654

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