Fluid dynamic lateral slicing of high tensile strength carbon nanotubes

Lateral slicing of micron length carbon nanotubes (CNTs) is effective on laser irradiation of the materials suspended within dynamic liquid thin films in a microfluidic vortex fluidic device (VFD). The method produces sliced CNTs with minimal defects in the absence of any chemical stabilizers, havin...

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Main Authors: Vimalanathan, K., Gascooke, J., Suarez-Martinez, Irene, Marks, N., Kumari, H., Garvey, C., Atwood, J., Lawrance, W., Raston, C.
Format: Journal Article
Published: Nature Publishing Group 2016
Online Access:http://hdl.handle.net/20.500.11937/16546
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author Vimalanathan, K.
Gascooke, J.
Suarez-Martinez, Irene
Marks, N.
Kumari, H.
Garvey, C.
Atwood, J.
Lawrance, W.
Raston, C.
author_facet Vimalanathan, K.
Gascooke, J.
Suarez-Martinez, Irene
Marks, N.
Kumari, H.
Garvey, C.
Atwood, J.
Lawrance, W.
Raston, C.
author_sort Vimalanathan, K.
building Curtin Institutional Repository
collection Online Access
description Lateral slicing of micron length carbon nanotubes (CNTs) is effective on laser irradiation of the materials suspended within dynamic liquid thin films in a microfluidic vortex fluidic device (VFD). The method produces sliced CNTs with minimal defects in the absence of any chemical stabilizers, having broad length distributions centred at ca 190, 160 nm and 171 nm for single, double and multi walled CNTs respectively, as established using atomic force microscopy and supported by small angle neutron scattering solution data. Molecular dynamics simulations on a bent single walled carbon nanotube (SWCNT) with a radius of curvature of order 10 nm results in tearing across the tube upon heating, highlighting the role of shear forces which bend the tube forming strained bonds which are ruptured by the laser irradiation. CNT slicing occurs with the VFD operating in both the confined mode for a finite volume of liquid and continuous flow for scalability purposes.
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spelling curtin-20.500.11937-165462017-09-13T15:45:17Z Fluid dynamic lateral slicing of high tensile strength carbon nanotubes Vimalanathan, K. Gascooke, J. Suarez-Martinez, Irene Marks, N. Kumari, H. Garvey, C. Atwood, J. Lawrance, W. Raston, C. Lateral slicing of micron length carbon nanotubes (CNTs) is effective on laser irradiation of the materials suspended within dynamic liquid thin films in a microfluidic vortex fluidic device (VFD). The method produces sliced CNTs with minimal defects in the absence of any chemical stabilizers, having broad length distributions centred at ca 190, 160 nm and 171 nm for single, double and multi walled CNTs respectively, as established using atomic force microscopy and supported by small angle neutron scattering solution data. Molecular dynamics simulations on a bent single walled carbon nanotube (SWCNT) with a radius of curvature of order 10 nm results in tearing across the tube upon heating, highlighting the role of shear forces which bend the tube forming strained bonds which are ruptured by the laser irradiation. CNT slicing occurs with the VFD operating in both the confined mode for a finite volume of liquid and continuous flow for scalability purposes. 2016 Journal Article http://hdl.handle.net/20.500.11937/16546 10.1038/srep22865 Nature Publishing Group fulltext
spellingShingle Vimalanathan, K.
Gascooke, J.
Suarez-Martinez, Irene
Marks, N.
Kumari, H.
Garvey, C.
Atwood, J.
Lawrance, W.
Raston, C.
Fluid dynamic lateral slicing of high tensile strength carbon nanotubes
title Fluid dynamic lateral slicing of high tensile strength carbon nanotubes
title_full Fluid dynamic lateral slicing of high tensile strength carbon nanotubes
title_fullStr Fluid dynamic lateral slicing of high tensile strength carbon nanotubes
title_full_unstemmed Fluid dynamic lateral slicing of high tensile strength carbon nanotubes
title_short Fluid dynamic lateral slicing of high tensile strength carbon nanotubes
title_sort fluid dynamic lateral slicing of high tensile strength carbon nanotubes
url http://hdl.handle.net/20.500.11937/16546